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Written CommunicationsEXHIBITS BEGIN HERE LL. ~ ~l-z /to Grace Schmidt From•_ Susan Sievert [spsievert@gmail.coir] Sent•_ Monday, January 11, 2010 5:56 PM To: City Council; City Clerk Subject: Written Communication, January 12, 2010 Attachments: ej_eip_kilns_web.pdf; ATTOO001..htm Written Communication from Susan Sievert Study Session on Regulation of the Lehigh Cement Plant Tuesday, January 12, 2010 Contains one attachment: ej_eip_kilns_web.pdf (Cementing a Toxic Legacy? Earthjustice Environmental Integrity Project. How the Environmental Protection Agency has failed to control mercury pollution from cement kilns. July 2008.) Dear Cupertino City Council, My family has lived 1.6 miles east of the Cupertino, CA cement kiln/quarry since 1949. For the past several months, I have not heard the plant like I am accustomed to, a very loud, intrusive machine sound that would oftentimes wake me up at night. -therefore, I am concerned the plant operators may be altering their behavior while the renewal of 1_heir Title S permit is under consideration. Many longtime residents have bought into the notion that the Cupertino kiln/quarry operation poses no documented health threat, and to this very day support and defend its operation without question. After all, we have never received any offi<~ial warning regarding toxic emissions, trusting that our City, County, and Federal officials would surely warn us if our health was in danger. Fears that have been raised have been dismissed with "the quarry has been here since 1939," as if to say some grandfathered in game of King of the Hill :shall now and forever trump health and environmental threats in the City of Cupertino. However, the timing of the lack of noise is very suspicious, and I am now deeply concerned some toxic truth is being concealed from all of us. In other words, if the Cupertino kiln/quarry has been operating in an environmentally responsible manner, then why on earth has it stopped -- and I mean stopped completely -- its longstanding behavior while it waits for what Earthjustice (a non-profit public interest law firm) asserts is the U.S. Environrental Protection Agency's (EPA) equivalency of a permit to pollute? By defying federal law, multiple court orders, and refusing to set standards to control cement kilns' mercury emissions, it's easy to conclude that the EPA has made a mockery of their assumed role as our taxpayer financed environmental watchdog. The following excerpts are from the July 2008 Earthjustice report, Cementing a Toxic Legacy?: Excerpt #1, p.l: "Cement kilns are poisoning our air, water, and food with mercury. For more than a decade, the U.S. Environmental Protection Agency (EPA) has neglected this health threat. Directly defying federal law and multiple court orders, EPA has refused to set standards to control cement kilns' mercury emissions. Now, new data from EPA itself show that the American public is paying a steep price for the agency's recalcitrance ~nrith poisoned fish, polluted air and waters, and increased risks to our health and our children's health. Mercury emissions from cement kilns are almost twice as high as the agency has previously acknowledged, and, in many states, kilns are among the worst mercury polluters. Thanks to EPA's neglect, the cement industry's rnercury emissions have not only gone uncontrolled, but also have largely escaped public :scrutiny. Having decided in the 1990s that it did not wish to control mercury from cement kilns, EPA has, until now, never attempted to tally mercury emissions from this industry." Excerpt #2, p.5: "Table 1. Ten Highest Self-Reported Mercury Polluting Cement Kilns, #3 =Hanson Permanente Cement [now Lehigh], Cupertino, California. Mercury 494 Ibs/yr" Excerpt #3, p.6: "Cement kilns in Cupertino, California, and Ragland, Alabama, were wholly omitted from EPA's 2007 data requests. Their n•iercury emissions data included in this report came directly from the Toxics Release Inventory, whiich are voluntarily reported by the cement companies. It is possible that mercury emissions: at these facilities could be much higher: Excerpt #4, p.7: "Table 3. Major Kilns Ignored by EF'A. Hanson Permanente Cement [now Lehigh], Cupertino, California. Clinker Capacity per Year: 1,497 tons. Clinker Capacity Rank: Eleventh. Excerpt #5, p.8: "Although there are other sites in California, the kilns at Davenport and Cupertino are of particular concern. In the San Francisco Bay urea, Hanson Permanente Cement operates a kiln in Cupertino, California. This kiln is located within a residential area in close proximity to several Cupertino schools. It is also located within five miles of the San Francisco Bay, which is currently contaminated with mercury. The Hanson Permanente kiln reported emitting a staggering 494 pounds of mercury in 2006 to EPA's Toxics RelE:ase Inventory. EPA failed to include Hanson Permanente Cement in any of its infornnation requests, leaving open the possibility that its mercury emissions could be even worst>_. ~~ <end excerpts> My other areas of concern are, 1) the plant consistently ramps up its output/noise at night (or on foggy days); we can see the plume of smoke, or whatever it is, over the horizon, 2) mercury is contaminating the Stevens Creek Reservoir and San Francisco Bay, and 3) that layer of dust that can be found on our cars is no doubt making its way into our lungs, too. A fair question for the EPA: Is that cement kiln operation poisoning us? Thank you. Susan- Sievert Monta Vista/Cupertino -. Cementing a Toxic Legacy? How the Environmen al Protection Agency has failed to control Mercury pollution from. Celtle7lt ~~11riS Earthjustice Environmental Integrity Project JULY 2008 F.A K'THJ US'I'IC:E Earthjustice is a non-profit public interest law firm dedicated to protecting the magnificent places, natural resources, and wildlife of this earth, and to defending the right of all people to a healthy environment. We bring about far-reaching change by enforcing and strengthening environmental laws on behalf of hundreds of organizations, coalitions and communities. We've provided legal representation at no cost to more than 700 clients. For more information, visit www.earthjustice.org. E IVVIRONh1EN1'AL IA'TEGR77"r PKCJJ L+CT (EfI'~ The Environmental Integrity Project is a nonpartisan, nonprofit organization dedicated to more effective enforcement of anti-pollution laws. EIP's research and reports shed light on how environmental laws affect public health. EIP works closely with communities seeking to enfor~~e these laws. For more information, visit www. e nvironmentalinte grity. o rg. i°r+crrr~ c~aeurrs PAG k. t: Becky Borhnorst, Downwinders at Risk Pnct a: Samantha Bornhors[, Downwinders ,zt Risk Pwcs s: Earthjustice Pwcc ~o: Samantha Bornhorst, Downwinders at Risk Pwce ts: Anacostia Watershed Society Pace it Becky Borhnorst, Downwinders at R isk For more information, please visit www.earthjustice.org/cement Questions and comments can be directed to ,fared Saylor at the Washington, DC, office of Earthjustice E A trrl t.r t~ s~r tc E 1625 Ma:;sachusetts Ave. NW, Suite 702 `Nashington, DC 20036 Phone (20:2) 667-4500 • Fax (202) 667-2356 Contents t Overview z Key Findings 3 Recommendations and Opportunities 4 The Mercury Data 5 Findings g Data Sources io Ignored: Mercury Pollution from Cement Kilns io Where Do the Mercury Emissions Come from? i2 Fly Ash i3 Why Mercury Emissions Matter i7 EPA's Failure to Regulate Mercury Pollution i7 An Overview of the Federal Regulations ~8 Years of EPA Delay 20 Recommendations and Opportunities 2i Notes 24 Appendix A. Kiln Data Analysis 2g Apendix B. Kiln Data Analysis Methodology 3i Appendix C. Normalized Mercury Emissions for Existing :ind New Cement Kilns TABLES S Table i. io Highest Self-Reported Mercury Polluting Cement Kilns G Table ~. Mercury Accounting Gaps 7 Table 3. Major Kilns Ignored by EPA iq Table 4. Where Cement is Made FIGURES io Figure ~. Concrete Composition ii Figure z. Mercury Emissions from Cement Production i3 Figure 3. Biooccumulation of Mercury ~o Figure 4: Timeline of Earthjustice Activity 1 :~ is tic '`°"'~, ement kilns are poisoning our }~y_ air, water, and food with mer- "~x..,_._f'~ cury. For more than a decade, the U.S. Environmental Protection Agency (EPA) has neglected this health threat. Directly defying federal law and multiple court orders, EPA has refused to set standards to control cement kilns' mercury emissions. Now, new data from EPA itself show that the American public is paying a steep price for the agency's recalcitrance with poisoned fish, pol- luted air and waters, and increased risks to our health and our children's health. Mercury emissions from cement kilns are almost twice as high as the agency has previously acknowledged, and, in many states, kilns are among the worst mercury polluters. 'Thanks to EPA's neglect, the cement industry's mercury emissions have not only gone uncontrolled, but also have largely escaped public scrutiny. Having decided in the 1990s that it did not wish to control mercury from cement kilns, EPA has, until now, never attempted to tally mercury emissions from this indus- try. EPA noti~ estimates that cement kilns emit nearly 23,000 pounds of mercury each year, far more than the Agency's 2006 estimate of 11,995 pounds.' Industry- wide emissions may be as high as 27,500 pounds per ~~ear~ The proc~°ss for making clin- ker -small nodules of cooked rock that are eventua:Lly ground into cement -often relies on fuels and raw materials that are high in mercury content. While the large quantity of mercury emissions from cement kilns is not widely known, it is hardly sur- prising. Sust over 150 cement kilns operate in the United States and, each year, they "<:ook" thousands of tons of 2 i cc rock -primarily limestone - at mere than 2,600 degrees Fahrenheit. To fuel this cooking process, cement kilns burn primarily coal. Both the rock and the coal contain mercury, a highly volatile metal that evaporates at room tempera- ture. Virtually all the mercury in the coal and limestone is vaporized in the cement production process, and t]ze vast majority of that mercury enters oiir air through the kilns' smokestacks. Mercury, an element, does not de- compose or otherwise exit the environ- ment once it has been released into the air. Instead it is deposited back to earth where it persists in soil and water and, through the bioaccumulation proc°ss, concentrates in fish and wildlife. Just 1 /70"' of a teaspoon of mercury, oar 0.0024 ounces, can contaminate a 20- acre lake and render the fish in that lake unsafe to eat.' People are exposed to mercury primar- ily through eating fish. Women of child- bearing age are often warned to limit their consumption of certain fish con- taminated with mercury. The Centers for Disease Control and Prevention reported in 2000 that eight percent of women aged 16 to 49 had mercury levels in their blood that exceeded EPA's own safe levels for unborn children." Because mercury is a potent neurotoxin, babies and children are especially at risk for birth defects, loss of IQ learning disabilities, and developmental problems. The purposes of this report are to re- lease the results of EPAs data summary to the public, to highlight the health and environmental threats posed by specific kilns that appear to have especially high mercury emission levels, to expose what appears to be gross under-reporting of mercury emissions from cement kilns, and to call upon EPA to act swiftly to set appropriate standards for this toxic pollutants The Clean Air Act required EPA to set mercury standards for cement kilns more than a decade ago. A federal court ordered EPA to issue those stan- dards more than seven years ago. Still, we wait. Key Findings EPA has estimated that cement kilns operating in America emit 22,914 pounds of mercury into the air each years Because this number reflects only non-hazardous waste burning kilns, overall mercury emissions from the cement industry are higher than EPA's estimate of nearly 23,000 pounds. EPA sampling shows that large amounts of mercury pass through ce- ment kilns, with some kilns reporting astonishingly high volumes. Absent emission monitoring and emission controls, most of that mercury will be released into the environment. A relatively small number of cement plants that use extremely dirty raw materials and fuels are among the worst mercury polluters in their states and, in some cases, in the country. Some cement kilns release as much as or more mercury than coal-fired power plants. For example, a cement kiln in Durkee, Oregon, emitted over 2,500 pounds of mercury in 2006. That same year, according to EPA, the top mercury-polluting power plant emitted 1,700 pounds of mercury into the air. Since 1974, cement production has increased 15 percent, but the total number of cement kilns has shrunk from 432 to 178 in 2006. lbday, ce- ment production is concentrated in the hands of a relatively small num- ber of large multinational companies. These companies operate larger cement kilns that produce more ce- ment.' Rapidly increasing levels of cement production in the U.S. mean that the cement industry's mercury pollution levels will continue to rise if left unregulated. Without proper regulation from the federal government, specifically from EPA, mercury pollution from cement kilns will continue and increase, add- ing to a growing public health problem in the United States. Recommendations and Opportunities EPA must swiftly follow through on its commitments to propose and adopt a mercury standard for cement kilns. .- State regulatory agencies should rou- tinely test cement kiln emissions for mercury. Continuous Emissions Monitoring Systems ~CEMS) should be installed to measure mercury emissions at every kiln. State regulatory agencies should re- quire cement kilns to install mercury pollution control devices. For more than a decade, Earthjustice has been a leader in fighting weak and insufficient regulations that failed to clean up mercury and other toxic air pollutants from industrial and mobile sources nationwide. Our work continues to yield results in cleaning up mercury pollution from some of the nation's biggest industri- al sources, ittcluding cement kilns, power plants, and incinerators. Along with our partners at the Environmental Integrity Project, we have compiled this report in an effort to emphasize the need for strong regulations that satisfy the long-stand- ing but long-ignored federal mandate to control pollution from the cement manu- facturing industry. Earthjustice, on behalf of many national and local non-profit public health and environmental organiza- tions, has filed dozens of legal challenges in federal court and won numerous legal claims resulting in stronger clean air pro- tections. In ~;oordination with groups like the Environmental Integrity Project, we remain committed to fighting toxic air pol- lution and making our air, water, and lands safer and cl<:aner for future generations. Tb learn more about mercury pollu- tion and thc: cement industry, please visit www. earth j ustice. org/cement. 3 Sc Y^ 4 ~~ =t '^:' en years after EPA was required to set standards for cement kilns, r•; "' EPA requested basic information related to mercury emissions from nine of the major cement kiln companie:; op- erating in the U.S.s EPA claims that it will use this information to propose mercury standards for cement kilns sometime in the summer or f ill of 2008. After a review of EPA's data, industry self-reporting to :EPA's annual'lbxics Release Inventory (TRI), and the data from the Portland Cement As- sociation, it is clear that EPA must act to regulate an industry that is emitting more mercury than previ- ously reported and continues to spew harmful mercury emissions into our air and water. EPA collected data from nine com- panies and ultimately released data for 51 non-hazardous waste burning kilns currently operating in the United States. EPA released data for all the kilns for which it has data except those owned by CEMEX, which has claimed that the information EPA requested -information directly related to the amount of mercury it releases into our air and waters - is confidential business information. All of the data considered were self-reported by the kiln companies. For a complete discussion of the data sources considered and methodology, please see Appendix B. The 2007 EPA collection requests were sent to the following companies: .w Ash Grove Cement CEMEX .x California Portland Cement Company k Essroc Cement Corp. ~ Holcim ~US~ Inc. LaFarge North America, Inc. .. Lehigh Cement Company -~ Lonestar/Buzzi Unicem ZZ;xas Industries, Inc. Findings According to EPA's current estimafe, cement kilns in the United States emit almost 23,000 pounds of mercury each year. This number is nearly double what the entire cement industry reported to the Tbxics Release Inventory in 2006 - 11,995 pounds of mercury released into the environment as air emissions. Based on the source test data that EPA collected and data self-reported by indus- try to TRI, the ten worst mercury emitting cement kilns across the country are listed in Table 1: ZO Highest Self-Reported Mercury Polluting Cement Kilns. The numbers pro- vided in this chart are based on the data set described in Appendix A.' Some cement kilns release as much as or more mercury than coal-fired power plants. As shown in 10 Highest Self-Reported Mercury Polluting Cement Kilns, based on source tests and industry's own estimates to TRI, several of these kilns emit over 250 pounds of mercury annually. The Ash Grove Cement Plant in Durkee, Clregon, has the dubious dis- tinction ofbeing the worst mercury polluter of any kind in the country, emitting more mercury into the air than any Dower plant, steel mill, or hazardous waste incinerator. In 2006 Ash Grovt; reported to the EPA's Tbx- ics Release Inventory that it emitted 2,582 you-.nds of mercury. Based on information Ash Grove submit- ted to EPA. in 2007, however, actual emissions may be as much as 3,788 pounds a :year. Note that although it emits the greatest amount of mercury (more than double the amount of the next wors~_ polluter), it has the third smallest production capacity of the kilns on the Tbp 10 list." o Lafarge North America, Inc., shows up on the Tbp 10 Polluting Cement Kiln list twice, at rank four and rank five with its plants in New York and Michi- gan. By Lafarge's own calculations the TABLE i. ~o HIGHEST SELF-REPORTED MERCURY POLLUTING CEMENT KILNS Basis for Production Capacity Mercury Annual Mercury (thousand metric Rank Facility Owner Location (Ibs~yr) Estimate tons of clinker yr) ,.'Ash 4G'~'r,"o~'q ~h~'~~~~t~~~'~rb'°~°t~~~'`~'~'r~~~""'+ .~j~8 't s°~~~'i'~e~t ~ i.'~~~~ ~~945~ z Lehigh ',~T'ehachapi, California. 586 TRI 958 3~ r':°,,~'{,rPI.I1CG~~~.v,,~.^,,+w~~ n: •.~~w ;seta ~~~'~n~~f~~' ~f~ e~7 ~".f~ " CernerlYia; `S r "v. a ± +1Yw +Y a. `* ~ N ~'Na v~am f ~,Ah i t~, 1 ~ .'~~' ~ N~; ~ .. J~W'.. ~.. J4 u~~a~'" ,~ ~1 '4 , 4 Lafarge Ravena, New York 40o TRI x.695 5 '-Lafarge ., ~." ., "AlpelyaMtth~gah4 i_k~ F("x~;^ ~~~yy+ ~~~~~ Soi'.,rGA~Sest ~- 3:z65 ' 6 CEM EX Victorville, California z7, TRI 2,7,7 7 ~.-Natlonal <.e ant ~ Rag~an2, Alabdrlta ~.- ~,y4 i' ~.l'° ty"g~ `' `' v w d ~(a" " '""*i ~. Sol ''t ~~' k i w~v ,,flY n .'S~~orYr~80~rA~b~FdiA: r'm~m~.. R»~.'f~n'$ ('~ ~D, .*Arv~aM~~w~'~~ fix' Y"w"t r~`~~!.~~'w~'AH".*nY~~', 8 Lehigh Mason City, Iowa ,84 Source Test ~3, u ,i,~y s~ "~F Gr7 °. ,t 9 '1~i?.~,,~C,N S: t~ ~'"^w.'.,. r..4rw"ns r dVF-, r .~ .. .. ~ .... ~ ~,` ,o Essroc Nazareth, Pennsylvania ,63 TRI ,,z8o Note that a[ the following locations, data provided in this table cover multiple kilns at one site: Ravena, New York - 2 kilns, Alpena, Michigan-5 kilns, Victorvill ~, California-2 kilns. S YO c t ~' n JR 6 c =4 kiln in Ravena, New York, emits 400 pounds of mercury per year. Cement kilns in Cupertino, California, and Ragland, Alabama, were wh~~lly omitted from EPA's 2007 data requests. 'Pheir mercury emissions data includ- ed in this report came directly from the lbxics Release Inventory, which are voluntarily reported by the cement companies. It is possible that mercury emissions at these facilities could be much higher. EPA sampling shows that Large arzounts of mercury pass through cement kiln:;, with some kilns reporting astonishinglpJ hi;;h amounts. Absent emis- sion monitoring and emission controls, most of that mercury will be released into the environment. When the actual mercury content for the kiln inputs (i.e., fuel and feedstoclt) are compared to the :;elf-re- ported numbers to TRI, there are often significant gaps between what is coming into the plant and what companies are reporting to EPA as exit- ing the plant. Companies report data to TRI that includes not only the air emis- sions from a cement kiln, but also mer- cury that may be treated, disposed of, or recycled rather than emitted through a smokestack. Yet, for the facilities listed in Table 2: Mercury Accounting Gaps, companies consistently reported "n/a" for these other categories, making it impossible for the public to know where the mercury is going. Some plants have installed scrubbers to control sulfur dioxide, and mercury emis- sions should decline as a co-benefit of sulfur dioxide controls. However, none of the kilns listed in Table 2 employs scrub- bers or pollution control devices designed to control mercury emissions. Lehigh kilns at Union Bridge and "Ifihachapi reported numbers to TRI in 2006 that appear to be grossly lower than their mercury inputs and clearly illustrate the data gap problem. The Lehigh cement kiln at Union Bridge reported to TRI in 2006 emitting only 35 pounds of mercury; but the number calculated based on EPA data shows the kiln could be emitting up to 1,539 pounds, an unusually large TABLE z. MERCURY ACCOUNTING GAPS Production Mercury Content TRI Reported TRI Reported TRI Reported Capacity from Inputs Mercury sent Mercury sent Mercury Facility (thousand metric (fuel and feedstock to Treatment to disposal released to Owner Location tons of clinker/yr) combined in Ibs/yr) (Ibs/yr) (Ibs/yr) the air (Ibs/yr) .. -m. . ts+ ..., . ~' es,~k s S#>, r.~ n. ,, X.. , 1. ."~. AU 1 bo ... .. z, _ x s, °. r Lehigh Union Bridge, i,g96 x.539 Unknown Unknown 35 Maryland 2 - nf' e^p w '~~„".KHi"'d`%~. •g 7y' ¢Y'~' rya y~g }~~~mlur rs y~,p '9Y~d~ r ~ e LBfSrge °I~`Sa4S r ` ~* itn, P~'r 6'~ ~~g ~"~zFF S~'~ ~'P s ~~$~' UnIC'I~ibWft'~ ~' t7' k n '~ 4• b ~i .c" '. x ~ t i ° &l~~liti'~la t~ ''a ~'`4~i a<Fi {~ 7 +rs. ~'~0 °'* h+`8m.r r u ° ~r, - u rw rS"~ si ;r .r rv.Y ,,ma~yy ~""}r ~w §1 +i ~ *t a ~'..~''~ ~,]Ara~iaa'.X, , v1 ,ni0 ap~{.~ u°, '.:'it r ~.. ~,ux ~v Sr~r"~'7 :! r A. x ~ 4 .~. yJ~C,Py(Yv'i~d'^ x -1 MAY nn~.e kA. rI 1". rv n .u ., ~ I J le Lafarge Harleyville, g78 zo6 Unknown Unknown 78 South Carolina 5p ' % ,~" pY '~:d+""s .~^rlw~ xqi Y~' 1# ' Y''~~'"re rt ! .r.N t r ~,.~r i ? ~ d ~+ TS4} iC~.a ~.5 "kCG ut9~`{.y '~ k~ t~'~ A~f~ ~~~ a ~~"~~c° ~ , <a ~4`~X,~i ~'a ~<5 h_ ' vx~ .«~ s ~ ~x'~, 2 -,ir ~nknown ,~ ~ .~ ~nk~now n~~w~, i r ~ ,,12 ~rovE ,.ash ngtotl! ri''a , , "~ , : ~ ( -.. , v, .w ^ ~ . ~ i ~ ~~~~ G ~ ... ~s"., ~ ,- .;,, . discrepancy, especially as compared to the entire data set. It is not entirely clear why there is such a large range. What we do know is: (1) Lehigh reported 35 lbs of mercury emissions to EPA's 2006 TRI; (2) all of Lehigh's reported 2006 TRI mercury emissions were air emis- sions; there were no reports of on- or off-site mercury waste; (3) in 2007 Lehigh reported an estimated amount of "mass in" of mercury, meaning content of the fuel and feedstock, of 1,539 pounds of mercury in fuel and ingredients. If 1,539 pounds of mercury go into the plant and only 35 pounds come out, what has happened to the rest of the mercury? Lehigh's Union Bridge, Maryland, plant is located approximately 75 miles northwest of Baltimore. It is the fifth largest cement kiln in the United States, able to produce nearly 2 million tons of clinker annually. This is par- ticularly significant given the plant's proximity to the Chesapeake Bay. As indicated in Table 2: Mercury Ac- counting Gaps, the Lafarge Harleyville, South Carolina, plant reported 78 pounds of mercury to TRI in 2006, but reported mercury inputs of just over 200 pounds of mercury on an annual basis. This plant, sited close to the Francis Marion National Forest, is preparing to more than double its current clinker production capacity from about 975,000 tons per year now to over 2.2 million tons per year by 2010. The fish in large sections of South C;arolina's water bodies are already contaminated with mercury making tYiem unsafe to eat, according to advisories from the South Carolina Department of Health and Environ- mental Control.' The cement i ndustry is rapidly expanding. Production capacity gains of nearly 2.5 million metric tons are expected between 2006 and 207.0." As the cement industry's capacity increases, the amount of mercu- ry emission::, if unchecked by regulation, will also increase. TABLE 3. MAJOR KILNS IGNORES BY EPA Company Kiln Location Clinker Capacity per Vear Clinker Capacity Rank ~~ r ~ a,.~4~+uav~rr.u ~~upt*,. fs Tltan'-/~rltAetiLa~~,~~Cf »'i~ . :4'I* ~~:s&~~~~~Fl~watr'a~..~~~.:a'^, ~f~. °, ..xi:~r~n~ni~i~~+lt s.'~ ~.`3.~'w.~a`' ~ .&'I ~:u th €.r ,. . Titan~America, LLC Cloverdale, Virgiyniap ,~+,g~ t,i38 to nsa~ zgth a ~E'~. : t 4'4 ,~ s. ~,s v 3~~ICj~`^~y~iliApS~I~~ x ~rwfi~ ,6'~ k fw""~s ~ 6~h.r °~tl~r ~w ~ ,~ MitSubii'hl.Ce7i'f,4nt~CQ~Q~~t'~"01~1 ~~ L~&1r~4 sao-.K,{,~ ~~~ ,a,~w 1.ds ±'r~~rwr~~' S.,.-. „w sar ;~"'r ,- 9t.~`r3~ 'r" ~i +~?+rc .^~a: Hanson Permanente Cement Cupertino California t.437 tons ttth Phdenhe C~iiil;n4 L'bt~~r,'~bi'S` ,~'r '~i z~ ~~ n~~y ~ ~~ ., ~~. .. `r.'"i,~~~'+..`k i~'.,,,.~3t .~."`n ..,, St. Mary's Cement, Inc. Charlevoix, Michigan ~ t,z;4 tons zest 7 °c 70 8 =r. ~S c: The cement industry continues to ,zooid public scrutinzJ as a result of inaction on the part of the U. S. EPA. CEMEX is the largest producer of cement in the United States.'" E]?A requested information from CErdEX in its 2007 informa- tion requests, but no information on mercury content of the kiln feed or results of mercury stack tests have been turned over by EPA to the public. CEMEX made blanket claims of confidentiality re- garding measure- ments of mercury emissions from its kilns natio~iwide. No other com- pany made such claims to EPA. CEMEX, like the industry at large, is expanding. It acquired Rinker Materi- als in 2007 and is expected to bring a massive new plant on-line in New Braunfels, 'I~xas, in 2009. 's EPA's 2007 data request omitted some of the country's largest individual cement kilns. As shown in Table 3: Major Kilns Ignored by EPA, EPA failed to request information from numer- ous companies with cement kilns that rank in the top 25 for production of clinker. Certain communities are bearing the brunt of EPA's inaction. Even a small amount of mercury can have adverse en- vironmental and public health impacts. There are several kilns throughout the country that are noteworthy due to their proximity to other kilns and populated areas. In these communities, EPAs failure to control mercury emissions is especially alarming. The largest concentration of cement manufacturing in the entire country is just outside of the Dallas/Fort Worth metroplex in Midlothian, 'I~xas. Citizens of Midlothian are burdened by five plants operated by Holcim, Ash Grove, and 'ryas Industries, all within a 6.5-mile radius of each other. Combined, these plants may emit just under 200 pounds of mercury on an annual basis, and thousands of tons of other dangerous toxic air pollutants.'s Although there are other sites in California, the kilns at Davenport and Cupertino are of particular concern." In the San Francisco Bay Area, Hanson Permanente Cement operates a kiln in Cupertino, California.18 This kiln is lo- cated within a residential area in close proximity to several Cupertino schools. It is also located within five miles of the San Francisco Bay, which is cur- rently contaminated with mercury.19 The Hanson Permanente kiln reported emitting a staggering 494 pounds of mercury in 2006 to EPFis Tbxics Release Inventory. EPA failed to in- clude Hanson Permanente Cement in any of its information requests, leaving Homes, schools, and nearby fauns are Zocated right beside a cemen' plant in Oa~enport, CA. open the possibility that its mercury emissions could be even worse. The CEMEX kiln in Davenport, California, is of similar concern. That kiln, located right beside homes and farms along California's coastline and only 40 miles north of the Monterey Bay Sanctuary, reported emitting 172 pounds of mer- cury to the Tbxics Release Inventory in 2006. The Davenport kiln is one of those for which EPA refuses to release data gathered in 2007. 'The Lafarge site in Alpena, Michigan, is a five-kiln plant, and in 2006 was the nation's third largest cement plant. 'These kilns collectively reported emit- ting 360 pounds of mercury in 2006. The Alpena cement plant is of particu- lar concern because it sits on the banks of Lake Huron and is in close proximity to residential areas of Alpena. Data Sources For the analysis in this report, an extensive review of available data on mercury emissions was undertaken. Data were assembled and analyzed from the following sources: .~ EPA, Summary of Cement Kiln Mercury Emissions (July 2008). ~+ Portland Cement Association, I7. S. and Canadian Portland Cement IndustrsJ PZant Information Summary (December 31, 2006). EPA list of hazardous-waste burn- ing kilns (:ZOOS). These kilns were excluded from the analysis because mercury emissions from hazardous waste-bur~iing kilns are regulated, albeit inadequately. ~- EPA-obtained data from several large cement companies in response to a 2007 EPA information collection re- quest. These data generally include: (1) mercwy tests and (2) data on mer- cury content in input (raw materials) for an approximate 30-day period in 2007. Data on rr~ercury air emissions submitted to EPA as a part of the 2006 TRI reporting. Clean Air Act Title V operating permits for various cement kilns. 9 ~- T4 10 c or. ~: _~ u '~ ement kilns produce cement, the ,~#~ ~~ main ingredient in concrete. The `~2>.,__,_,~^~ terms cement and concrete are often used interchangeably, but cement and concrete are quite different. Cement FIGURE i. CONCRETE COMPOSITION . Air . Portland Cement - Cravel or Gushed Stone Sand - Wa[er makes up just over 10 percent of any con- crete mix.2O See Figure 1, Concrete Compo- sition. Worldwide, the United States is the third largest producer of cement, behind China and India.' Thirty-nine companies produce cement in the United States, and the top five companies produce over one-half of all U.S. cement.~~ In 2002, the United States consumed 103.8 million metric tons of cement.23 Where Do the Mercury Emissions Come from? Mercury emissions from cement kilns originate from the feed materials (e.g., limestone, clay, shale, fly ash, and sand, among others) and fossil fuels ~e.g., coal, oil). In general, the amount of mercury emitted by a cement manufacturing kiln is proportional to the amount of mercury in the fuel and feed materials due to the volatile nature of mercury at the tem- peratures encountered in a cement kiln." For a description of the cement manu- facturing process, see, Figure 2: Mercury Emission from Cement Production. With regard to limestone, EPA recognizes that: A significant portion of kilns' mercury emissions comes from limestone; and Limestone's mercury content varies with location. Similarly, with regard to the fuel sourc- es at cement kilns, EPA recognizes that: A significant portion of kilns' mercury emissions comes from the fuel they use; .• Individual kilns use widely different fuels, including different types of coal, petroleum coke, scrap tires, fuel oil, and natural gas; and, These fuels have significantly differ- ent mercury contents, as do different types of coal.~s Many factors can decrease the quan- tity of mercury emissions produced at a cement kiln. These factors include the use of fuels containing less mercury (e.g., natural gas or coal with low mercury content), cleaner raw materials (e.g., limestone with low mercury content), kiln design (e.g., dry kilns as opposed to wet kilns), and various types of control FIGURE 2. MERCURY EMISSIONS FROM CEMEIVT PRODUCTION w. ,r1.~ mewls+wtr~l.. ~olscwl~d t-~ pgllMi ff wfrlo vn[ w I eni ram {raMpln ,pear.!-7h!41'~'wanr al+twai/ rw®>iC•n r.y n. i.. aYV~ril of w[~.uy`r r wrrrrtrmlroeorn. Mrw ~puis u~ ~, ~ fb S !. Yrw ~.. O[a A QirtT Mr[. L1n1t+nMnt. [!.e )nrne[Y Npe[tr1[I :. cnnerR d laio^lMI If Iy1L .alw.+Y+~ r+a<.a~ .a...f.~r V r.~..n. oil Va+~[....t 6r..W +Hh Sw 1°'St1la}~O![y!1Ut GfO~r ~MII/, BFl 11~ f>A[. 6,%~l RI[Gl1C.It /i411Fy n{11. 1 ~~armase ry}Ya>. tl[N A ~I~. ~'ww Kl~i N1w b~v~R~s~: ~~ a wury oR mr[o ury i AM Furl Up B4rw1 n1 rar n1aln l.b eir K+i mo nla1l~ ~uaM1'b rlii ral ar rari.d r w=a[q ^.>s1 R• r~r [[rt.rvfa [Ppvcl+ N ae..r nl [I+r op(xr,11r crl rl rl rr ~N~r<JI'Nf ^~wa+rHC1 Mrrpwatrw almvr ~5 pMan [v hN sa n.. aF`~ anbo-. Tha d.-rrl:M ..-sr3xa pel~rraYY1 by dGn ~.ert a,m p.e ran..1[1<rleM .,f+ el~/,v n.. rearrdN,n R+nss•+v n1 mr.+Trwc ~'' : •M a Tp , .~..... y .~+~.1 n -. cr'~ ~< ..1 utrn !•~ ~~ i r. v y 9nf11r1t up MS 9[I.U. rsU2 k r s .1 W ~. Yra rry Mme[ .:r ~y 6. TIVI.sptsYSOn .41v po..ap Mrsv~h IM rafvy kY1 sl.sse[ s rnd.d. ~.vld v+d L/a[r d•t wwr+ pMMAr, WM [ h kr_ ryf [1'1e otmen[ hnm nsni M [g ico qu~9~rV 1' M_ `t+d KoAU ri nl lapa~ v.a .A.n v.~d la c,ar...v-...w ra u.a ccr,.w :,. wt i.~ ..FIB ' 4nla Rrn foal IA prfrtl MY) wN[nN h4a1 :[K/d4 uvr, N ~ a nafatlranl~ ~[[tr rsrgy alo~[o rnd iN r,~cpwvgi W. 6+ Rra C+. oI Ih+. ~I'INf W1i !N\IFi In r[, ni'y 114'h" a av[1 1c1tr 11 Yc o' Yc 7 12 of y _~ technology (e. g., particulate matter control devices, such as baghouses .and activated carbon injection). Some kilns have already reduced their mercury emissions by making changes to either their raw materials or fuels or by using additives.~s Not only do some kilns have consistently cleaner inputs than others, but some kilns are deploying pollution control equipment that reduces mercury emissions. Yet, EPA has failed to require similar reductions at other plants. 13 i. o' YC ~ eople are exposed -°to unhealthy levels .. of mercury when they eat mercury-con- taminated fish. Figure 3: Bioaccumulation of Mercury, depicts how mercury can end up in our food supply. Three forms of inor- ganic mercury are emitted into the air by cement kilns -elemental, gas- phase, and particle-bound mercury. The latter two, comprising 50 percent of all mercury emitted, are believed to deposit locally and regionally around the source.' Once released into the environment, bacteria convert this inor- ganic mercury into organic mercury - methylmercury FIGURE 3. BIOACCUIVIULATION OF MERCURY w~:'_"- t n.~ ew ~ , . ~ ~ '-' ~ ~ p h . ~ _ 14 C ;< is the most common form -which the:n accumulates in fish and shellfish.~a Methylmercury quickly enters the aquatic food chain and accumulates as it is passed from the smallest organisms to those at the top of the food chain, like walleye and bass. (See Figure 3.J fish at the top of the food chain contain between 10,000 and 100,000 times great- er concentrations of methylmercury than that dissolved in the water.29 Once in the hu- man body, mercury acts as a neuro~~oxin, interfering wit]i the brain and nervous system. Exposure to mercury cars be particularly hazard- ous for pregnant women and small children. During the first several years of life, a child's brain is still developing and rapidly absorbing nutrients. Prenatal and infant mercury exposure can cause mental retardation, cerebral palsy, deafness, and blindness. Even in low doses, mercury may affect a child's development, delaying walking and talking, shortening attention span, and causing learning disabilities.ao TABLE 4. CEMENT CAPACITY BY STATE' ........................................................................... State Percent of Industry ~. -„ c>ilti~ ~~ ~~. .. o ` ...~.,- u,n ~a_ .. __ ... ~ _ ..~. _ . Texas I2.2 % fi~rr,, ~ ~ ~ '"-P! „n..wvsaFiz~ «.~~,~,~ u ~..~'.;_ ~;e:rv, ~'a; .:, n4i .. ~ "-{.~,,.. «~~'x~~.."~'a.. °'~. Florida 6.; % M~ ~~ ~ ~, ~~Sf:iL of ~. 'Alabajn3' r ' ~ r ,", e~:a~' S ~ ~+, ~; 54 P * .. From the U.S. and Canadian Portland Cement Industry. Plant Information Summary, December 37, 2006. The Centers for Disease Control and Prevention estimate that 8 percent of women of childbearing age have enough mercury in their blood to put a baby at risk of cognitive and developmental dam- age." The National Academy of Sciences' National Research Council estimated in a 2000 report that approximately 60,000 children per year maybe born in the U.S. with neurological problems due to in utero exposure to methylmercury.'~ Mercury poses a threat to adult men, as well as women and children. In adults, mercury poisoning can adversely affect fertility and blood pressure regulation and can cause memory loss, tremors, vision loss, and numbness of the fingers and toes. A number of studies have found an association between mercury concentra- tions and heart attacks in adults. In one of those studies, the authors reported a 69 percent greater risk of heart attack and a 93 percent greater risk of premature death in individuals with hair mercury concentrations of 2.0 ppm or more, com- pared with those with less than 2.0 ppm." It is well documented that mercury pollution is currently a major problem for many states, with nearly all states having at least some fish consumption warn- ings for particular waterbodies. Across the United States, in 2006, mercury was known to have contaminated more than 14 million acres of lakes and 882,963 river miles. In 2006, 48 states issued fish consumption advisories, warning citizens to limit how often they eat certain types of fish caught in state waters because they are contaminated with mercury, 23 states issued statewide advisories for mercury in freshwater lakes and/or rivers, and 12 states have statewide advisories for mer- cury in their coastal waters, including all states on the gulf coast and the majority of the eastern seaboard.'" Kilns in close proximity to water bod- ies are a serious health concern. A study conducted by the Florida Department of Environmental Protection modeled the contribution of local atmospheric mercury concentrations to measured mercury levels in fish. A correlation was found between levels of mercury found in locally caught fish and recently mandated emission reductions in local municipal and medical waste incinera- tors. At one location, 92 percent of the observed total mercury deposition could be accounted for by local sources.35 Not surprisingly, a disproportionate number of states bear the burden of the industry's capacity. As shown in Table 4: Where Cement is Made, in 2006, 44 per- cent of clinker capacity is found in just five states.36 According to the Portland Cement Association, clinker capacity in the United States is expanding and contin- ued growth is expected in the coming years.3' In 2006, capacity reached an all-time high. Additional gains of nearly Earthj ustice has ad- vertised in newspapers and on billboards across the country about the dangers of mercury from cement kfZns. The ad shown here, which ran in a newspaper in Midlothian, 7Y.xas, notified Zocai residents of potential changes [o a cement kiln operating permit and the need for public comments. Similar ads appeared in Michigan, New York, Pennsylvania, Florida, and Colorado, telling EPA to clean up mercury from cement kilns. 15 S sa Y~ 2.5 million metric tons are expected between 2006 and 2010.30 Unless appro- priately regc~~lated, as capacity increases, mercury emissions will also increase. 16 `c U L .y L` ~< C 17 YG y4 An Overview of the Federal Regulations After years of foot-dragging by EPA, Congress identified 189 hazardous air pollutants (HAPs) in the 1990 Amend- ments to the Clean Air Act. Mercury is one of those Congressionally listed air toxics.'s Today, the primary way that EPA regulates air toxics such as mercury is through Maximum Achievable Control 'IZ;chnology (MACT) standards.4O The Clean Air Act requires EPA to identify categories of facilities that are major sources of these air toxics and to set emission standards for each category, such as cement kilns."' When EPA issues MACT standards for an industrial category, such as cement kilns, it must set standards for each hazardous air pollutant that category emits.42 For each HAP, these standards must require the maximum reduction in emissions that is achievable considering cost and other factors."' Well aware of EPA's tendency to cave to industry pres- sure and issue weak environmental stan- dards, Congress also included absolute minimum stringency ("floor") provisions in the Clean Air Act that apply without regard to cost or EPA's views about what is achievable.44 For the existing plants in any category-, EPA's standards may not be less stringent than the average emission level achieved by the 12 percent of sources with the lowest emis- sion levels."s For new plants, standards may not be less stringent than the emission level achieved by the single lowest emitting source.46 Congress enacted this law in 1990, and re- quired EPA t~~ complete its MACT standards for cement kilns no later than 1997. In direct violation of this law -and in defiance of repeated federal 18 .L ^c court orders, EPA has yet to set any mer- cury standards for existing cement kilns. Thanks to EPAs recalcitrance and neglect, uncontrolled emissions from cement kilns have continued unabated for the last decade, at a rate of approximately 23, 000 pounds a year. Years of EPA Delay Three times in the last ten years, federal courts have ordered EPA to set emis- sion standards to control cement kil ns' mercury emissions. But EPA has ignored these orders or sought to evade then2. In 1990 Congress amended the fed- eral Clean Air Act to require EPA to set standards for the emissions of air to:cics from cement kilns. The standards were due in 1997, but EPA failed to act, and in 1998 Earthjustice filed suit on behalf of the Sierra Club to force EPA into action. In 1999 EPA did adopt a rule regulat- ing toxics from cement kilns, but in that rule EPA failed to set a limit for mercury."' EPA wrongly claimed that because it found no cement plants us- ing control technologies specifically for mercury, it did not have to set a mercury limit. EPA's cement kiln regulations were unlawful.48 In particular, the D.C. Court of Appeals found that EPAs failure to set emission standards for mercury flatly violated the federal Clean Air Act. Five years after the D.C. Court of Appeals found EPA's failure to regulate FIGURE 4. TIMELINE OF THE LEGAL ACTIVITY .c'Yx ~yi s feF p. zl7 ~j'~.z~`dC Cfn~'S~s1011 ~'OT tO I 8 d ryrt ~ ~.5- '.-:' x ~~a.~..i„ n ° #~ a ,, s 6"y ~',1,+ »LUr t b- t G .~1 #~,: 1 CU ~; T v, A,a ~ "f y ~, , .* ,~ ~ T y mx ?fit kM_ i ° pollutants~'~ncludlrig , ; ~ ~ ~ ~ ~orrl en ts « r ~ ~ ~ hyd~o~ari~oFi~ ( mercury from~cemeni - .. FA ' •. kilns Assn: propdsed rule again fails to establish emission;. , .-~- ,~ .a f.V L v fit., rPt~X ^s - t0]Cltdrd'~'C`2[rC~` w x a ~ y ~ 2" vr- ~~'{ hx .~h, t-i ?s'~ ~" x' i$ F ~~~ # `~`.: _. .- ' '- a ,. ~' .. t a > ~ ~.,t p ~ ~~' '.~ mercury emissions from cement kilns a clear violation of the Clean Air Act, and despite a 2005 court order requiring EPA to propose rules, EPA yet again refused to set regulations to control mercury emis- sions from this country's existing kilns.49 EPA's scofflaw approach to toxic emissions from cement kilns has drawn increasing attention from states that are grappling with their mercury pollution and from citizen groups whose members are affected by this pollution. Nine states and seven environmental groups combined to challenge EPA's most recent refusal to set mercury standards in a 2007 lawsuit before the United States Court of Appeals for the D.C. Circuit. SO Under intense pressure from states and local and national environmental kilns eYnit and orders EPA to set the missing standards (case referred to as National LimeAss'nv.EPA) and public health groups, the U.S. Environmental Protection Agency finally indicated that it would set mercury emis- sion standards, as stated in papers filed on February 20, 2008, in a fourth case brought by Earthjustice on behalf of Sierra Club, Downwinders at Risk (TX), Friends of Hudson (N`~), Montanans Against lbxic Burning, Desert Citizens Against Pollution (CA), and the Huron Environ- mental Activist League (MI). The States of Michigan, New Jersey, the Pennsylva- niaDepartment of Environmental Protec- tion, New Yorlc, Connecticut, Delaware, Illinois, Maryland, and Massachusetts also filed suit. EPA's announcement marks a dramatic shift in EPA policy which, until now, had beers to resist requiring mercury controls for cement kilns. 19 io o' y- -~.,.., ~, ~~ -°~ ~> rn= ~ o ,ry .;,,.~ y .. m ,,; 'courts 2C2oo orae[;rn' ' ... ~ ;. .. . . ~_..,~ ., ~ NAtibnol Li»-ie'AS4M' ,~ F_ ns uit~E$"7ifi"f Ci~ ~~,~ .'~a w ' ,, f 1 ~'- of i~~$riE ~ x v ~~- ~ ,~;i r y.. ~, r~a,~ ' s ~ ` ^` ~ '~[ ~ ~ :~a..:s„ `~el~"as ` eiti'i t d"`t " ~ ~ g , rc t that EPA has^plain ,_ u ~ ~ . .,. `~`t~i~~ards'fof~ct~me_nt _`=' . ;,, , : _ a To`xiG Legat:y'~' statutory duty to set kilns in zbo9 document~ng~mercury ~missidr5'stahdards .,~ ~ emi5s_iori '~roirr s for each•ltiazi;~dous, ~; , y _cement kilns across- "~ ' air pollutant that an E '' the country industry emits ; 20 c x y >c EPA must foZZow through on its cosvtmit- ments. In a recent court document, EPA stated that it would release a proposal for a cement kiln mercury standards' This is the first time that EPA has publicly acknowledged that it will finally abide by court orders requiring it to set a cement kiln standard for mercury and that it will comply with the Clean Air Act. EPA must now follow through on this pn~posal and release a final rule in 2009. EPA.'s proposal must not repeat its past litany of complaints as to why such regulation is too complicated. It is not. States should require specific testiseg for mercury emissions. Even once a st.m- dard is set by EPA, it is incumbent that states implementing permitting programs across the country have access to u7~-to- date information. Source tests will t>enefit both the public and permitting authori- ties. Neighboring residents will be getter informed of health risks. Permittin€; authorities (the states) will have be~cter N~". ~.. _~ information with which to set permit limits and take enforcement actions. Monitoring must be added. Continuous Emissions Monitoring Systems (GEMS) should be required for mercury on all kilns. GEMS will provide real-time data on emissions at the cement kilns. This technology should be promptly installed at kilns nation-wide. PoZZution controls must also be added. State regulatory agencies should not wait for EPA to set standards, but should imme- diately require the kilns within their juris- diction to install pollution control devices specifically designed to capture mercury, such as activated carbon injection. EPA claims that it will propose a standard to limit mercury emissions from cement kilns in 2008. Any failure to issue such standards must be viewed critically by the public and prompt public officials to ask why we must continue to be exposed to this toxic pollution. Notes ' EPA's current regula[io ns distinguish between cement kilns that burn hazardous wastes as a fuel source and those that do not. This report addresses EPA's failure to regulate mercury emissions from non-hazardous waste burn- ing cement kilns. EPA's own Tbxics Release Inventory (TRIG does not distinguish between hazardous and non-hazardous waste burn- ing cement kilns. The 2006 figure of 11,995 pounds includes both types of kilns, making the. new finding on non-hazardous waste burning kilns at nearly 23,000 pounds all [he more significant. ` See Appendix A, for this industry-wide emis- sion estimate. As reflected in the appendices, this number is based on a mix of data from TRI, source tests, and input data. While the input data numbers are probably skewed to a high-end, assuming 100 percent pass through of the mercury contained in the kiln fuels and Feedstock, it is also likely [hat emission data reported to TRI and through source tests are in some instances underreported. ' Janet Raloff, Mercurial Risks from Acid's Rain, 139 SCI. NEWS 152, 153 (1991). ' Centers for Disease Control and Prevention, 2003. Second National Report on Human Exposure to Environmental Chemicals. Avail- able at http://www.edc.gov/nceh/dls/ner. H[m. EPA used the CDC data to estimate number of newborns at risk. See Mahaffey, K., et al., 2004. "Blood organic mercury and dietary mercury intake: National Health and Nutrition Examination Survey, 1999 and 2000," Environ Heath Perspect, 112:562-570. http: //ehp. niehs. nih.gov/docs/2003/6587/ abstract.html. Cement kilns are sources of air pollution For mercury and many other toxic air pollutants. Cement kiln systems release numerous haz- ardous air pollutants into the environment, including acetaldehyde, arsenic, benzene, cadmium, chromium, chlorobenzene, diben- zofurans, formaldehyde, hexane, hydrogen chloride, lead, manganese, mercury, naph- thalene, nickel, phenol, polycyclic organic matter, selenium, styrene, 2,3,7,8-tetrachlo- rodibenzo-p-dioxin, toluene, and xyle nes. In addition, the Hazardous air pollutants released from other components of the kiln, such as the clinker coolers, raw mills, finish mills, storage bins, conveying system transfer points, bagging systems and bulk loading and unloading systems include arsenic, cadmium, chromium, lead, manganese, mercury, nickel, and selenium. See National Emission Standards for Hazardous Air Pollutants: Proposed Standards For Hazardous Air Pol- lutants Emissions from the Portland Cement Manufacturing Industry, 63 Fed. Reg. 14,182, 14,183 (Mar. 24, 1998). ° See Appendix C, July 2008 EPA data sum- mary. Please note that this re Elects non- hazardous waste burning kilns only. ' U.S. and Canadian Portland Cemett[ Industry Plant Information Summary, December 31, 2006, pagers 2-3. These industry wide numbers refie:ct both hazardous and non- hazardous waste burning kilns. ° See February, 2008 Declaration of Peter TSirigotis, Director of the Sector Policies and Programs Division of EI'A, filed before the D. C. Circuit Court of Appeals in pending Cause No. 07-1046, Consolidated with Nos. 07-1048, 07-1C49 and 07-1052. ' All production capacity numbers come from the U.S. and Canadian Portland Cement In- dustry, Plant Information Summary, Decem- ber 31, 2006, Portland Cement Association Economic Research Department, Table 13. See also, Appendix A. 1O Hanson Permanete Cement is listed in Ap- pendix A as Lehigh-Hanson Permanence Cement. Leh .gh purchased this plant in 2007. See, U.S. and Canadian Portland Cemert[ Industry, Plan[ Information Summary, De- cember 31, 2(106, Portland Cement Associa- tion Economic Research Department, Table 3. According to the Portland Cement Associa- tion, in 2006, this plant ranked 42 out of 112 U.S. cement kilns for capacity to produce clinker. This rank includes hazardous waste-burning kilns. See, U.S. and Canadian Portland Cement Industry, Plant Information Summary, December 31, 2006, Portland Ce- ment Association Economic Research Depart- ment, "Fable ] 3. For a discuss ion of [he planned expansion, see U.S. and Canadian Portland Cement Industry Plant Information Summary, December 31, 2006, page 4. Information on South Carolina mercury advisories can be found at: http:// wwwscdhec. ne [/environment/water/ fish/ downloads. hcm. U.S. and Canadian Portland Cement Industry, Plant Information Summary, December 31, 2006, Portland Cement Association Economic Research Department, page 1. " See U.S. and Canadian Portland Cement In- dustry, Plant Information Summary, Decem- ber 31, 2006, Portland Cement Association Economic Research Department, page 1. 's U.S. and Canadian Portland Cement Industry, Plant Information Summary, December 31, 2006, Portland Cement Association Economic Research Department, "Fables 2 and 3. 's See Appendix A for the following values: 19 ibs. from one TXI kiln, 31 lbs. from three Ash Grove kilns, and 146 ]bs. From cwo Hol- cim kilns. " Non-hazardous waste burning kiln sites in California include: CEM EX's kilns in victorville a(Id Davenport, Lehigh's kilns in 'Ibhachapi attd Redding, California Portland Cement's kilns in Colton, Aill ito, and Mojave, and the Hanson Permanete Cement kiln in Cupertino. 21 re y^ 22 c: '" With regard to clinker capacity, this is one of the largest plants in the country. See, U.S. and Canadian Portland Cement Industry, Plant Information Summary, December 3'., 2006, Portland Cement Association Economic Research Department, 'Fable 13. Note that the capacity ranking includes hazardous was G; burning kilns. '" http://wwwswrcb.ca.gov/sanfranciscobay/ water_issu es/programs/tmdls/ sfbaymercu rytmdl. shtml. 3O "lbxas Aggregates and Concrete Associationz, "Frequently Asked Questions" at http://tx-taca.org/uploads/files/ Concrete 96 20and 96 20cement 96 20faq. pdf. " Portland Cement Association, "Cement and Concrete Basics" at http://www.cement. org/basics/cementindustry.asp. Portland Cement Association, "Cement and Concrete Basics" at http://www.ce ment_o rg/ basics/ce me ntindustry. asp. " Portland Cement Association, "Cement and Concrete Basics" at http://www.ce menc.o rg/ basics/ce men[industry.asp. 2° 70 Fed. Reg. 72330, 72333 (Dec. 2, ZOOS). '~ See Docket A-92-53, Item II-A-46 at App. P.. zs 70 Fed. Reg. 72330, 72333 (Dec. 2, 2005). " Glenn Rice Fr James K. Hammitt, Northeast States for Coordinated Air Use Management, Economic Valuation of Human Health Be.~- efits of Controlling Mercury Emission from U.S. Coal-Fired Power plants (2005) [hereinaf- ter "Harvard/N ESCAUM study"] a[ 5. 2H Washington Department of Health, Statewide Bass Advisory, September 2003, citing EPi1. 1999. The National Survey of Mercury Concentrations in Fish. Data Base Summary 1990-1995. U.S. Environmental Protection Agency. Office of Water. September 1999. EPA-823-R-99-014. " Washington Department of Health, Statewide Bass Advisory, September 2003. '" http://www.nrdc.org/health/effects/ mercury/effects.asp. Centers for Disease Control and Prevention, 2003. Second National Report on Human Exposure m Environmental Chemicals. Avail- able at http://www.cdc.gov/nceh/dls/ner. htm. EPA used the CDC data to estimate number of newborns at risk. See Mahaffe,;/, K., et al., 2004. "Blood organic mercury and dietary mercury intake: National Health and Nutrition Examination Survey, 1999 and 2000," Envimn Health Perspect, 112:562-570. http://ehp.niehs.nih.gov/dots/2003/658T/ abstracthtml. " Palmer, R.F., et al., Proximity to point sources of environmental mercury release as a pr~- dictor of autism prevalence. Health Fr Place 2008), doia0.7016/j.healthplace.2008.02.077, citing National Academy of Sciences, 200(1. 'Ibxicological Effects of Methyl-mercury. National Academy Press, Washington, D.C. " "Harvard/N ESCAUM study" at 37-48 (citing Salonen et al., Mercury accumulation and accelerated progression of carotid atheroscle- rosis: Apopulation-based prospective 4-year follow-up study in men in Eastern Finland, 148 Atherosclerosis 265 (2000)). J° U.S. EPA Fact Sheet, 2005/2006 National Listing of Fish Advisories (July 2007). Also at, http://www.epa.gov/waterscience/fish/ advisories/2006/tech. pdf. '~ Florida Department of Environmental Protec- tion, Integrating Atmosphere Mercury Deposi- tion with Aquatic Cycling in Soutlt Florida: An approach For conducting a'Ibtal Maximum Daily Load Analysis for an atmospherically derived pollutant (2003), pages 56-57. 's U.S. and Canadian Portland Cement Industry, Plant Information Summary, December 31, 2006, Portland Cement Association Economic Research Department, Table 11. Note that these capacity numbers reflect kilns chat also burn hazardous wastes. U.S. and Canadian Portland Cement Industry, Plant Information Summary, Dece mbez 31, 2006, Portland Cement Association Economic Research Department, 'Fable 2. 1B U.S. and Canadian Portland Cement Industry, Plant Information Summary, December 31, 2006, Portland Cement Association Economic Research Department, page 1. 39 See the list of hazardous air pollutants at Clean Air Act § 112(b). °O when the EPA sets MACT standards For pollutants at particular sources, these stan- dards are referred to as National Emissions Standards for Hazardous Air Pollutants, or NESHAPs. State and local environmental agencies may obtain approval from the EPA [o run programs that administer MACT standards. For a state or locality to run a MACT program, it must demonstrate that the state or local MACT requirements are just as stringent as the federal MACT requirements. °1 For hazardous air pollutants, the Clean Air Act defines a major source as any stationary source of emissions that has the potential to emit at least ten tons per year o£ any single hazardous air pollutant or at least 25 tons per year or more of any combination of hazard- ous air pollutants. Clean Air Act § 112(a)Q ). In 1992, EPA published an initial list of major source categories chat includes Portland Ce- ment Manufacturing. 57 Fed. Reg. 31576 (July 16, 1992). For the requirement [hat the EPA set standards for each source category see, Clean Air Acc § 112(d)(1) and Nat'Z Lime Assn v. EPA, 233 F.3d 625, 628 (D.C. Cir. 2000), amended on den. o£ reh'g 2/14/2001. °2 Clean Air Act § 112(d)(1 ). See also, Nato Lime Assn v. EPA, 233 F.3d 625, 628 (D.C. Cir. 2000), amended on den. of reh'g 2/14/2001. O3 Clean Air Act § 112(d)(2). Clean Air Ac[ § 112(d)(3). °s Clean Air Ac[ § 112(d)(3)(A). Note that in source categories where there are fewer Chan 30 sources, the limit may not be less stringent than the average achieved by the best five performing sources. Clcan Air Act § 112(d)(3)(8)~ °" Clean Air Act § 112(d)(3). °' EPA published its final rule that failed to set any limits on kilns' emissions of mercury, hydrochloric acid, and toxic hydrocarbons. See, 64 Fed. Reg. 31,898 (.lu ne 14, 1999). °a Na[Q Lime Assn u. EPA, 233 E3d 625 (D. C. Cir 2000), amended on den. of reh'g 2/14/2001. O9 70 Fed. Reg. 72330 (Dec. 2, 2005). The 2006 final rule did contain mercury standards for "new" cement kilns, those for which construction or reconstruction begins after December 2, 2005, but EPA immediately commenced reconsideration proceedings on this aspect or the rule. 71 Fed. Reg. 76518, 76524 (December 20, 2006). Those proceed- ings are still pending. so See EPA's February 20, 2008 Motion to Govern before the D C. Circuic Court of Appeals in Cause No. 07-1046, Consolidated with Nos. 07-1048, 07-1D49 and 07-1052. s' See February', 2008 Declaration of Peter 'ISirigocis, Director of the Sector Policies and Programs Division of EPA, filed before the D.C. Circuic :ourt of Appeals in pending Cause No. 07-1046, Consolidated with Nos. 07-1048, 07-1 D49 and 07-1052. 23 -24-- Appendix A __~. KILN DATA ANALYSIS ;a Capacity Study = in t,ooos Study Range- : of metric zoo6 Range- High Dry/ tons/yr TRI Hg Low Hg Hg High EPA "' Company Kiln Location ST ZIP Kiln IR Wei ~n clinker (Ib/yr) (Ib/yr) (ib/yr) Basis Scrubber Resp? k 4 N r n r ++^' a. ~ i a + ~x rt~ yr ?fi + n9 N~ F ~ '~~ ~ L C ~ a:. Ai`m~,tron " r~, ~a ~({ `ay"£ ~ap'~~ ,,r+~aK~ ! ~5 y( ~;q~~1~y(i u~^yga.~) d~' gy~~ f~a."~ h a r~..~ 1ai p,g #PP taa~ Tr a ~ryµb. ^.$ 6 ~` °' ~ {{.gg0~~~".a~g;'"9p~i"' "~ y ' , CS ~'°£} y ~ y .Ar nn^rYr~,~~ O r R 'C.N~1F'. S~y¢ 'M, .~ Ieµti1 P W~.ab~:~ S c `~ v .... Ce 2~t M'h.~21 Y"^f.~M'rM hrv s,~ }K'P ., mM''m tt,. ~.1P ~ ~Jifl '.F nL W.n. nr~ I'FNr~ " rr f;. .:. ~ ,eP - Ash Grove Durkee OR g7go5 t Dry 894 z,58t z.58t 3.788 Test Yes F :. ^_,~a BM1 ?r+ti a i y~r ~y Q, SR: w $M ~ f r3 Y Aa .~ ~ PouS d"a A e5 ~ ~'~ 9~ a t , ASh~4rbVe ~` Inkbr(i-irs ~`~17~a ~. IS3~~?"F,~yAFm ;.. ~}w~$d ~k~~~~~, ~ ~¢^, ,, ~0~.~s s~r+,_~~"~, q~.w~ ...t <r nr fi '!.;l'e5^ . Ash Grove Inkom ID 83245 z Wet t44 ~" °i" r; 0 5 " ~aq #~G ~. " r , I ~ Yes N ro4" #'PS M.^'°'N x . x N JN k~ Gw =' Lr v A°~' Tp F ~: e i : ~a-0t f F "s N _ VS R'^ ~;~~ p 5 v "1: Ash ~roye :r otllsLl~e.,i5 .„~V ~,r ~,aF~w ?<, F.:'`'"~r-~.'~l*,': ~~'9t~r'?.;, ,cam +~.~«~ h"37 .'. '~~~°,~'n, a. .'F•-~ i D ~ P Yes. .. A ~ aw ".arx, an ~.~~~wsi Sc~u '' Ash Grove LouisvPlle NE 68037 z Dry 55t v . a 7 06 ~ + +~-,~,~T, >f ~ b~i4g,." Yes ~y rpr q ~.'~I v 4 84~~° k~ r %a ~~r+' .. Pa,++a ~~4 C aaz ~ Qsxr~~P +' S x ~~ r" I `' °K erA`= . n+k '~ ~~'1Y~i~ry„~'t a'`~ ~fi~ 4 }. k°~y h, .,N d . t e • 4a ~tlr Y r l'Y ~ d F,{ "5'.` a ~^' ^N4~wi ,ac . , Ash V`$ve `e'~`",~y `b ~~Vt~a°"~"" n ~"1"'~''~ ~~~3{~~nt c~ G ~~t4, ~+{z~'~ k',a, " (V°o ~itl 2 Y`",• y I~put '' Yes Ash Grove Nephl UT 84638 t Dry 833 t53 t53 t67 Input Yes (LeamPngton) „ Ash GYOVtl ," Sea![)e i- 'VVAs, ~ .~~~~ ".. 04 '~~ ~ ., ; a~ "'fir !t 6Y5'~"^ 't+ ~ t,'2 ~ ~W~2i ra +~' ~2 !:' ~I iipuY i a? : ;~~ a ~.: ..Y~^s+. . Ash Grove Midlothian TX 76065 t Wet z9t t.5 Yes Ash Grove . .~:MFdlbthia~ . ,TX~;I ~~o65`s.. x 3="r ~~E. ~., x^Z~~? ^,^,; 3t t Y>%?; 3t TRI t" °i`"s ~"" "Yes' Ash Grove Midlothian TX 76065 3 Wet zgt t.7 Yes Buzzi Chattanooga TN 37405 t Dry 8t6 No TRI Buzzi Fustus MO 63028 2 Dry 537 '. " ZZ{~ W S~~ yyrr .2 l'U uh i~P. u~ t ~,b4 Ti4b V r+~, 5 %1.+,$7 ' 'exl"~~ ry~: , ~~~!''n ~ N~'A$~~. ~ 7~~ a . BI l .11t 5A j., "" . :: e:. `! a: „ , :> , Buzzi Independence KS 673ot z Dry 8t ' Buzzi itldepende''1ce w . ~b['y ~ ` $t~'~' ~ f:"~o1 ; y' ~ ^ *. 't, " , r , , ,~ ~ ^ Buzzi Independence S 673ot 4 Dry 8t ~. K BuY2~l~ e5L7y ~gI ~ y +-':s 4 . '~ d~:y~~~k'"T idfi %:iJ ~L!~,Y ~~~R ~~ ~ '~'! ~ 4~ , X; » > _ v a . . . : . v , Buzzi Pryor OK 74362 t Dry t9o i 'z w x Kan w `d~a° '' P 3 r ! Q t w:. ~~r t8§ura:: ~ Di• ± ~ '~'"i'~~ ~~' #"n5r~ +., Bi. z y. ,ry 2 . , wr_ . Buzzi P ry o r 6 2 OK 7 3 Dry 274 4 3 } w, ryry~~ .pµ.~ i I ~' ~) ~ i'R 11 b¢ ~ y C 9yF ~S * 'j M1 Kt$ 28 ?~ ~I ~ ~~ BU;,zlr . trf te Y QW ~ . yj~~~k . y v V YAn x.wn .. ~ r~$~ «la.Sr Buzzi Stockertown PA t8o83 z Dry 558 Buzzi ~ _ M aryneal TX 79535 z Dry Buzzi. Mir~neab~„,~ ,7X .R.7R~~~'d.~P'^"~" °n~D, 7P:~:% California Portland Mojave CA g35oz t Dry Cement 2? ?? a> a ,a ; x~"~k ~ +P e s "?} °~ rt "" .. . :jetx. d ]> No '++?' + i 1 pj S r -x i No ! ~ ` a ~~T u 9 ' 1rM, = '~" ~ x xe• No ' ' . r ~~ g~+" N o ' ~: ~~' pia »~ o• rv•~ a a'1 N ' a (x '{~ ,Y hi .t tl { a2.( t „ ... ..w ... 1.M t5o t.375 t3 t3 zo Test Yes 25 =i io S is California Portland Rillito AZ 85654 4 DrY 969 °'t sxr 'O' Cement '' ~' ii". ~} ~5 L J" o 14 P r 4 ~, FI ~~Y~,~,x• ~ s+9Ty a 4 ~ I '°' ~ b l i r 1 a ~ s - ~~~ ~ , r _. Cap)°~'y ~ ~ ~SY't~"J["n~99~"~'~"~.'.~` ,7$i~1"~~~~ o~ ~~1"~ Fr~eWe`E~„ ~91ir'"s ~.!') i .t~' Wit I ' t ,l No? _" Capitol San Antonio TX 78zt7 Aggregates z Dry 6oq ~' No ~ ~' ~ -. C@inEx ~~ BrooksvillE`" ".FL: ~~ :;q61 r, ,,'. ~rj~.,~ li r~629: „~ - "6.. _.;. Nb. Cemex Brooksville FL 34614 z Dry 629 ~~i wQ le~~ No `~ ~ ~wP "~ " "'~' r 5 tl> ': ,> 1 ~' A ~~g yI SLS µ nbw Y ~ 4 ~i ~ i .. Ce~dR ~w k~~ w :~'1 k T<v qg,~~., +r ~`l ~~p r ° We r3_gdpyi, .i t4~~ ~ d r is ~ 1`+ ~M°~ -~.~ °~..d4w§ F ?dS,+afid.~'~'J~'n'"~ rwl~w~+,"^'r ,J s'u''..?,'2r Cemex ~ Clinchfield 'GA 3i ot3 t Dry .755 g 38 No Cemex Demopolis AL g673z t Dry $53 pNv~o TR..hy No ~.. N%n'- 0 ~t q~ ~cm 3. <Y y 5Z ~'d y.AAUi ~W Pb' °i ~' ~. T pVA-~L~~ l6 .y N.1 +~ ~4h'1K~d~e~"~ci ~ .. ~.-...'y„" «. ... ,,. ~^ ..:..a!9F _.s ..u. '~~.. .:. ,.". r,. s <:~.,,. ... iw -4a~ .~~w r, ~~-.,N°h " _.+,rb r`ti i7;'%fi7x ,~.9 , V - Cemex Louisville KY ~ 4oz7z t Dry t,4o7 36 No ., .,~ °. - ~ ,~~" ~ ~ ~ i~~ ,. m '~zc". ' b'" a `.v ~$ r,'e¢ ~~ ~3, ~ i °^' '~""~' x*~`6~~-'f~, ,,~ r »a ~"~a~. ~ ' u~i "~t:~t~"b` Ceme>t ..t Lyons ,~:_ e. O,= ,SO~:,: i e. ry ''. '~~7 ~ '' v "s,. i ... .: r, . ~ ., _ .~.+ .~... ..w,.. Cemex - Rinker Miami FL 331 8z t Dry 985 z5 No Materials i ^r w,:' N1W, J t ~. (': "U. t'{ry` ~e4 i "l, Cet~SekF 1 eM, -O'@~e~~'$~..+,~w 9r an'SC'''`w'N'~~~Y~G 9 7 6 6 Cemex Odessa ~ TX ~ 7 _ S S ~.~ } ~ '~i t ~' 'MN' 9b~y 7 _ N n"{k~ ~~,~~ CN IV ,~l<k~~.,~:w~u~~XS ,,` „~'3,5'll .~`~'~ ~'~.»'; ~"._ ~''. .i`~~ ~.}'~ o +'' a '~'~ No z 87 z D ry yn ~ ~ u Cemex' ~.VieTalYllle?,~'ti ~A ".~7~y<3P+"~,~ .. Cemex ~Victorville CA 92394 r , ~ y~ ~-., k~rX.3.:~x1 o49^:i~u+" ". .. :.,. ;No a 3 2~'7 ~ ~ No z Dry 1,668 ,~.i5 5~; ;~ _ _ _. _ . Cemex Wampum PA 16157 2 Dry z5t 'ale, '}~ i'y ~"~.. No . ,. ,.. , " .. .. - . ~. Ceniek ' '"VV°atl'iPu'm~;° P/~~:~- ~ 1~G'i $y~~:~ 3 x~i r brky' x~gi~: ~ epma~.1.'.:. .. ~''~Y, No `:,r ~. ~ . . .. - Cemex Xenia' OH 45385 t Dry 692 z4 No 4 u N r hi .w a _ ^iu ~ .:, n f ~ "? 1 ~ c .- i ~lx„~^ x. i L " i+~. i9~' ~^~ Dragbn + ~ ~ a ~'F i ~. _.~ rr.Yk .~r,7 ro ~+W ~ t: a ~ J, s d" ir~u, . ~ ""7 v' ~~,T ^ t~ ~' ~*F ~x^'y .~y' .,$, 'rf~a~;am +,~:~~ri~"r~" ~ .~ No Prod(Ycts ~' Y~O/r1$SL {7 Fi V lv ~'(' ~ r~ ~ ~~ ov~ ~r31.1 GTE .,.4914 '.~ ~;~ ', 4 s"~. +.. .. i ~ '~+ a c ~ n ~ .J £ 'Iw T~~ n u QOm rl d axe p~" ~'~~$4 n~nMiw ~ ~''~bAd~~~A.^y,"~~F~,°~.~YS$+xi `emu p'~i~x ',~i_~.w~+a!. -~`n'r ~,rGT"r ;r,a-. , ~~' ~'h :<'~C`,.,,,~ P,? Y _t -. s~ ~ <, q.Mw. ~ 4Rh, Y~ IxYN Sin Eagle Fernley NV 89408 t Dry 226 No Materials Mit.4~C vrx~aa b' ~ . '..' ~m'. ..~.:. ~~,.' y~-*-* '~:+~i1T> .4~:~ ~'ua ~. W~~ .~tn, rx' # .,'.` Eagle La Salle IL 6t3ot t Dry 6oz to No Materials 4 x~a ~ec a ~ ~ ~ ~' ~ '~ -i ~~~°` ~i B ww~~' i ~.~ ri "~k " !c Ma 6Idj.~ar a>.~ .. t:;fl i, .. ;M~ ,. ..._ .+~,.F "~'~t w ^4 ~~~~X`~'~r g 'r ~~ ~ No Ea le Laramie WY Szo7o z Dry 4ot o ~'t'~ Materials ~ x '11y"' Essroc ;="Bessemer PJ1~ 26113;'" ,. j~ " /elk, a~.#~7 ~. ~ ~ '.,d5`~~ ., a.~~,."+"c "FRIh":.: ~ Yes :, ,v" , . `. i ,tit' `" ~ 2'$f ', Essroc Bessemer PA t6nz z Wet 368 9t Yes Capacity Study in t,ooos Study Range- ofinetric zoo6 Range- High Dry/ tons/yr l-RI Hg Low Hg Hg High EPA Company Kitn Location ST ZIP Kiln # Wet in clinker ~Ib/yr) (Ib/yr) (Ib/yr) Basis Scrubber Resp? yg Capacity Study ..... in t,ooos Study Range- ofinetrtc zoo6 Range- High Dry/ tons/yr TRI Hg Low Hg Hg High EPA s Company Kiln Location ST 21P Kiln # Wet in. clinker (Ib/yr) (Ib/yr) (Ib/yr) Basis Scrubber RespT E°IssroG '~:'1=r~`dePl~k~z:r ~TM`i)" ~ti'>b~+% rota ~~x,~~'~"~VVeh`~~i, Y~. .t54;. ~, ~~ ',u` ~'~ ~ t~~'Rl.~;: ~ ~ ~F~ n 49 ~ , wVes , y 3~~ .~ 3~ i~ ~ t""' Essroc Frederick MD m7o; z Wet t54 "~ ~, .., , ' ~ . Yes -' E9sroc ~:,`Marttnsbu.~g" WV' z54br' :"•r :` ~ Wet ~ ' •<•. _zo8" - 'z , " r: ''t,Rl-2 ,' ~ .":o Yep _ ,r Essroc Martinsburg WV z54ot z Wet zo8 tqg ,": z ~' . ,Iq.g. Yes ^Essroc. ~y„ klarkiYisbifrg ~ z5'q~'ir' %-3" -~ yi/et~ '~'t" z- ~ ;? ~ ~ a u +~~~r~s" ~~'`! ~ 6 r r ~'"~'~ ~ w 3 " +~~Y~'s3` - LL , .n s'~ 5 d : . ~. Y> r~: r . . I,a 1~ 4.4a a 4v ae d1. x. .. Y.q}a ~ _ = Essroc .Nazareth PA t8o64 t Dry t,z8o t6; No 5, .. s ~ Est h~ ~tl " . ,w~awi+~ ~u..: _ ~ arc: , m R:-w ~ . . .. " i : x "9 r~: .. ,, a4.1 f"tYt"1 r"~: . Essroc Speed IN 47t7z 2 Dry 62t , 56 Yes GCC of America Rapid City SD 577oz t Wet. t48 No " '" i`.,k ,'..',- :.uM, ~ 3''. „'^. W°'~ v*'r S ». aW i J~~ a ~I"`.:, -: >r ~ r . Americ~~ ~>•,^zRapid'tity SIS" 57'>oz?,~ ~~'~"^" ~I¢x~~i e;a"h t~$}""`*~- t8 '. uFx ,t~*k.if}"d'v ,~'~ < Nb GCC of America Rapid City SD 577oz 3 Dry 602 No i'i i .. , r , x ,. xxn ~, , GCC Of ~`„ ry " + u.. „ 3,.,~ Y cur Ar,Her~>"a' `a~'[Ylera;j '.. NM,{~~87b59~~.,ha D~i 9,,~ 21d "ta j~~9 ; `. ia. x "~~~ .~. +. m'°~..,~4 `e y'r .~, rSJ ~J'~`' µ ... ..t r, cr eM~.i 7 i, . 'i. r, a r 1. ~'' ~~':~, e„'da ' '' n : "^, ~ ' r,J~r ~a x. GCC of Tijeras NM 87059 z Dry zt6 (i t~k `'~' No America r ,,r. Kt,3, Ci).~Iryt~rN fG '4w4- h Vic- ,R s~[s$~~'L~'i~~ p"t~'~ i, .''~4~a ~. 'ar ~"3~y~~'Y r. ~~""3ii ~*~,M~ Na ~ea~ x ~'r' i' r F° av`.' , '! ~e t,~ i 4:a:m ~~1 ~ 4 "a`5 ~ r ~+~ ~ ~, ~' z F ~ ~~ x a ~ S ~ « ~ ~ J ~ "P70` '. t efu~t~ +. e~ if ~ %~, `~ d6 ?~ „y j~s w}. }~ ~' +)k+u utX •~ y w„a i sF^ ,#~ rp ;. > -~- ..'9 3i. ~ n. .7 ~ t m na.ta .v'e ~ 1.. Ey'at ~~~ "Y~~-n ~"ai.~+~:.,~t+~.), w. ~'3~"~" Holcim Ada OK 7g8zo t Wet z5z No ` Holcrf '~'~' 7ida " '' a ~ ,.an ~ ~~tr .~rr.w x=m s t,vr , ,_ 65 x e • parrs ., a r ... ~I~`"" i ~4$zony S~' .unyt~'. c zb~2~, ~"y,n.~~e.r .~,, ~"g ~`; r ,y y,, r, s a "~'~, . Holcim - St. ~ ~~~ ~ ~ ~ ~ - ~ ` Lawrence Catskill NY tzgt4 t Wet 58o t No Cement 5 Company Ho1Ci Nt .'?:u'`ro':~~', D,U 7~dee `; .+.H,,,iv1•,, .~' ,,+99 ~ A 'i "-5 ° e '~~~ ~y~ fit.,;, ,~ "~~' 'i'a t `~ ~.?rYy ~ rr^ ay.~ r.,~9try. a~ Te, sh" ?' '~a"~s:, T ~ '~ni..` ~~sT k,~~'Rar.. ..Mv»' ¢ ''d+.l~'1.., _ rJ,tw ..; ~.._ t^ r Y -wt x° i ., .a, w.':Kt .. Holcim Dundee MI g8t3t t Wet Ott ~,~-~ay' No Hblckk~f~w„w y5c'r y ~.a~^ .,F^.• .....:. ~' ^~ M_ ~ ~W ~ °. f~~,+~r"~.. . ~ ,~r ~~+~'~aq a yrrct~ "mC~~es " .,xN:. ~p^ v ,w a,e.. ~y 3 i+ ~°~ _,r fi.` ,:d m~ ~Cf~r, r.tt~4"M~e ~dw, t' ui~^ o-e.'~^ Holcim - St. Lawrence Hagerstown MD zt7gz t Dry 548 48 No Cement Company Holcim Mason City IA 5ogot z Dry 3 5 0 W~ .~"rot~''~9y~^~ No I-fale[n'1 ~~iltdltlt}l~~'ri' , µ 8 ,, ~;;~ ~O~f` ~a'L~rv`~ r"~uryw'" `;"4°.9a7 "~"lx '1'~ '" ~ '' lira sA.°.,.~ ~ r 34 q„~,,,L ~ ': t Yea' ; ' e3i ` ? °F~ i - ~ .:. _. , .. Na.x _ .+n re ._ < ~ i1X , U 4~~ . : ^ , ~ • Y'2% „u .. Holcim Midlothian TX 5ogot z Dry t,oz8 ~;`., nz Test Yes ~ ^~-1o14j~'rr`i;,... -~~r8a.~e.. i, r'll~d``~i ,8A.0$O"~. .~~ ~ ~„a ~fi°x~z?a .qit :~,I . n '.~'k~ .. I~JO~• E^ Holcim Theodore AL ;658z t Dry t,gg7 7; No Holcim r ~brk3 a 'aThM~e ~fv1T "° S9xSz'! k ~ zy7tx~ 'Wet' ' ~ 7 ~ ~~', N`e.`. <. ,, , _ , y t . Lafarge Alpena Mt 4g7o7 t Dry ;go 54 Test Yes r, q ' ~ ... eg . i - ~!p`$"'C, v ..., .. , o. .. : .:~~. .... .+. -.'..'N n , rvr: ,... M . ,. :a Mi? •;:: t r` ..P ... ~.., ar:^# Y, ~. , ~ Lafarge Alpena MI 4g7o7 3 Dry 387 360 360 50 Test Yes t:afa~~e~ 4 ~~y/j ~ na w;,.. ~'~°~ ~Aa ~ Mf :; ~~ 078:, '"~ta"'4 E ~+ ~""~;@s'~ G"`tzg~:; ~ 'Y'es ~`~k~r ::.., : . ; , " , . Lafarge Alpena MI gg7o7 5 Dry 5 4 4 to8 Test Yes Lafa7geu x^ ~ '13fiffalo t1A .~.~ 5zyi~~, ta~ ~ y+ ~ ;~@ '~rY w~ ~ ~'r '")"' '"{"p"'C, 1zg" 22'x x f}# v.~i "t"'~ '`x Yestl in ~ . y a ~ : a. 75 .. , ~~ , ., ; Lafarge Calera AL 35040 t Dry t,467 36 78 z58 Input Yes Capacity Study in t,ooos Study Range- o£metric zoo6 Range- High Dry/ tons/yr TRI Hg Low Hg Hg High EPA Company Kiln Location ST ZIP Kiln # Wet in clinker g (Ib/yr) (Ib/yr) (Ib/yr) Basis Scrubber R,e~sp? La argrw&~ a ~ ~~p4 *' "~.+ r f~. "S~~a'-a la''~ r "'~*"'~~ -"~Tfe~ tr~:. -_:.; ~'F i 'p'~'h, a ~;iy,.; < 4 :rr. ,,. +;, ...,.d,w .'~R .d'~i ~a.o h ,. _ wt `~ .~'/ `~},rya ~. yw`A ~ +r", "MI", ,m 4,qi"~; ry+~r.+..,' Grand Chain r -'~"'~"'(# .i I ~~~' ~~' x ~~ ` Lafarge IL 62941 z Dry 549 ~~~"~?.^~ .~~~ s ~ ~'~ Yes OoPPa) 'r n ia.xk~` Lefart~ e, > I-`aYl ~ r~~S ~ xl "c~ D r"~* ~ tLr .,~r `h ~.° r,. YaYi.` 5np1i~ ~v1~eSt„`: Lafarge Ravena NY tzt43~ t Wet 847 No LaPa':. a kave~ ~~ NYd. t~54 ~ ~ ' z e3' '' ' ~4~ 400 . . .~ ~ z~~> ~ , ` ., ~ ~o-.'.q;. _.. .5~,. .g ~..~ ~ . raw ~, ..~ Lafarge Seattle WA 96to6 t Wet 387 30 30 39 Test Yes .t Sx x t~• m° x .+5 ° a ~5 aye a "v.w n Ax a ~ x rz .,t '. ~~N n°y.~ w ~ rr ' ~ tv, Lafarge'"M .~5'd$`~(~`~i2e~l,~~Ot ,~~~.~.5 ~r~~~ " r~,'~>, ~~~u ~~%~,~., ~ h~~~a .', ,r.3G~3„d •r atl'"e$t.:' ~'e's°, .. Lafarge Tulsa OK 74116 t Dry z95 No r',~k: rl^~# r k ~c e rA' *W"u au 7~r kr~ z k.~r r ~, 't "~ ~ ~ ' '.,No Lafarge=.~^' .. '1'4jSal;~?;"A '~~.k: r~ yr4,'. ~.YeP~~~eo"~.,~~- »,-:n fi.~~, t ',t:, ..T ~r ~#.„`*s'Y~~irFd. .. .. w9.,::. , ..a ,. Lafarge Whitehall PA t8o5z t Dry 419 z4 TRI Yes t a , . w ~~'~ 3 w w I° a ~"9k '^.a3,kt~!' & '; 'r+ b°ii;;,~ 6i w r bt + ^` Lafa"r8e . n 'ikttehal~7~ ~ j , PA's "" 2`M$'~,g~'Ai p..+ . ? ~~' ~ ~. t ~,z l!. ~6 ~~. .. .. '"Yes' Lehigh - Buda TX 786to t Dry 1,134 t6 No Texas-Lehigh ~ . a x * ° Yi a y n~~,'' ^e°~ ~i '3 ! C { ' o i'1 + ~ ,_ M* '",~- ni F9 '.,~ ~ . ~r ~ -. LeltlBh ~ ~ it ~ L s/~ ' na" a +a,,x~3 a ^tr rk'n m ~ wa ~,F a; ~ygt~. 4 ti ~ y, c4 t ry4 ~a N_µ F . I-(9i136ri, >j i,..~, rr rr'•~ 4 " P dS ix+ -x ~ ~, wra ,~R' ' ~* g~~- s 1 in ~ ' ~ 1V0 A ,$7 k F V e Y 4 S AS t I tY~jY b b ~, 5 7+, rr r~ V P~ l 4 pkey ~ p Girl c ~ r w T v(' b,'~.!e .vim u a '~" 'f a .r' ~{ Ft + h t i " PerIY1A,~'Irkeiiog, r tt°w vau± y~vr ~~ ~ hK ,z r. i h ~ C5.7~ ~ ya ~• ~ .Va , ~r ny^~ ~ w~ ~'h u H 4 r y~ 7F t~. Cerrlent, a . ~ ~.;ia~~ F,x~,S "~'i~ ~x~tz'"r `~,5. '~„ .. ~ ~., ~ ~' *w"~~.~ ~.., ~*" *' W;:e.. .::P~,.~~. ~- x> '~rkr ~,~, Lehigh Fleetwood PA 19522 t Dry 533 66 Test Lime Yes W~yy~ .r+~ ~ - i ,., .. - S6 86 `~ .. ;, ~'+,,:% Injection t~„'T~ v ~ ~"~' ~n4~3a~'l y. :'. ~ :~~" ~, ew'.« in BH ~'Mt„.., ;, Test/ Lime Lehigh Glen Falls NY tz8oi t Dry 586 tz tz t2 TRI Slurry Yes y y~ Injection +3tt~ :k~;d'kti ° Su'~~1 i"`LS li ~~~~~ '~' e ¢-.~!i ~"'~°~ ~w S~yNM k` 1~~~,''(rr~. 6'*~~ +'~d .:,u1~5 P 3~~rw7,pr./ t`'~ e~ _ . ,~< ,. Mxa ,~ ., ~. Le17iBM n.` .: ,~'.e'~Sttwt, . rux.•s. fi . t~.. m" r., iu..4~ . °~~ir-x' S' - # rG s ..~.. ~.. ,. ~ .. ~~. ~-~ c Lehigh Mason City IA 5o4ot t Dry 731 184 148 184 Test FGD Yes *'` Cra ~"° m„x x M1` wip y~~„d~x +,~`y,n+ e~3',` r ~'~~ ~ ~ ~~cu. L!°(i'igpp , 5 Mi'tc ~I.T~'-'a^.t~a 4~j~`ik1 ~ l~~, ~. ~&~'~ ~~,~,x ~~D ~ytr.fi+r ~ ~^t. qyy ~+ 33~ " .~ ~ ~ r<'j'RI'_ 1 Yes ` Lehigh Mitchell IN 47446 z Dry 251 }, , is~, ~° 33 '*t~.g ,. ~ Yes Lel`i'(gh "i Mitc)ta ~4 ~' _`I'~I~"~.. ~47~~$+' .~';'' I7!Y'Y.',<. 27!~ "b^' _ ,1• 3 r:. .. . •~, dge MD zt7yt t Dry ~ 1,996 - 35 35 1.539 Input Yes Lehigh Union Brie ur.. ~, ai+'E ~~xrtc '` r x,~ i~ .; e~F k `ti ~,p' a:x NO~TIF z ` s ` T`e3ti' r Yes ' LeF~gh sWaeo .;. "r, >m.{' it' ~~~j °. , r t ~~ .~.. ... , ( _. Lehigh Redding CA 96003 t D7 592 9z No ,~uu iy tt o, = y W tt n _ 1 S ; ,t: e. r r ~ ylx _. y n n„' _at w ~1r ra F >.~ .~ + ~w : ,Le'hfgh,fi f_ ~.,u~~Ue~a~~ ~~a~~, awj4t."F~~~6~k~~~~.1!" x~r'r3;.rs~,5~ rN6.r"5~S': ,...58¢s a,1 ~48,.. Input g~'~'.M^yS;i,, -,Yes-", Mitsubishi Cement Lucerne Valley CA 92356 t Dry 1.543 t6o No Corp ,, r+V"t { r tt v , +6Po • y r r.~ ~` y ~1 Y+^:; ':` X nJ : e w x `. + t>e,u '•4 '''~ ~ w l~' ty~ two y ,~ 6 Monarch r r '~¢ r ; } ti r r ~+?y' gL5 ,~ ~x F dr n ^°,°y~ r y, to 4, ~ ~~ s ' r `~l~ ` _ C!" qnL 'H~$i4''t6bl t r~~,~"9:~ .~b~yB t C~!l l~ ~~i ~, ~~R}~ wr tt .a/ a ~ I } , v i, r x ; cort+anY_. .: i~a ~.~~ ~~p~w"aS ir'"~y~ Nr ~ ~=t wW w~+1] i _y . ~~a .,gp,•yeG~ ~ ..rr,. ~•~.` •=,g'_ ~ ~'/'~ ... Monarch ~ ill~iv No Cement Humboldt KS 66748 2 Dry 449 ;~ . Company ~ ,;,~,}_ _ 27 ~' s o' xc National Cement Co. Encino Lebec CA 91436 t Dry t,o33 59 No California 28 c`t _~ Gipacity in t,ooos of metric zoo6 Dry/ tons/yr TRI Hg Company Kiln Location 5T ZIP Kiln lF Wet in clinker (tb/yr) Study Study Range- Range- High Low Hg Hg High (Ib/yr) (Ib/yr) Basis Scrubber EPA Resp? St. Marys: Dixon IL 6tom t Dry t6t No Cement St"'(vlSu~~..~~~ e fil` .~ r".~~k4 n<}iy ~ nar ~)~'~r~kp"$w~ r ~~5~' ~ s~ r ~+M'~ =' t{ t~..s~`-~ ~ ~' - ° y:4 ~.,,~.~:. L`CMGI'1Yd v g 1~~i1f1~r~, J;y.h Lvp. n ~ ~Nuz,~ ~." »^~~ rt m^ 5 ~k. ~~~~,. ~ ,6 . M?r..w , ,+, .#.: ir~'1 t r his ., t5 t» , , ~. x St. Marys Dixon IL 6tozt ; Dry t6t No Cement 9~[, ~p ~y, r ay' ~ St %'aY dF"e~~ '~,~4y r ik3 d, ~' S ? ~g `~' ~ ~ ~ dy„~',,,n ~~ex~,.r ~>~°~fjaw ~Y~~ rR"9fa y~C .i `P'Ny n ''' : 4~ '~7 ~ J u f' i x51y ) )Aru .~~0. %~Ckn~i'~,°`"f7"a~kbt1,~.. 1.~~I; eu ~~;i r'" ,~~a .I r x-,''~".'? ~ ~..'~~.. ~F~ - _ as» .r. d„f"`r , Suwanee American Branford FL 3zoo8 t Dry 8zo 55 No Cement 'TXI' ~.+,~v1id~O~Fplari, ar +yfi06 :rti .~ 'a, QtYs Y196gs,"' + t~°' ~ ~''i~'05",tf b _ ..1a.-"" .u~~E :Sa`:. S,! ,ff~rkcY,,~~.' ,u ~~ ._..~ ~ Tr. . 41"PIN '.~`.. ~ .33 C, Gk.4 ~ .k' Fr .:~: TXI New Braunfels TX 78t3z t Dry 780 87 No n c w~n r' ~1 rm^`Y%w x T u~" ~~e}~nx X26„}' ro°~r .w h;a~" .~:w~ :i~°°N~"', +^tTX~u~u ,~ ~t,e,~Vf~a[~„l~~i, to ~. at 3~~~~~ 't~~oS4 ru .4n~ •...~.. _rd ~0i. ~s;s S~~1, ;:r i^ „- ~:" ,« .. ..°. TXI Oro Grande CA 9zg68 2 Dry t6t ~nrL,~n~wr"_ y,~ q a ~~ g y;~ +~ No l'SC~1., .,... k~.C`S"t~ G~rB'fk~~e'~a ~~Gc•,~'s' `~.~~°,$~~' w"~~~+'~`s~-" .H~.l,Z~~.rt'. "~`,'~~Fr'1,~'~"~~#,~kv"~ ~ 'i+ . , .F ... ~ No TXI Oro Gratn~de CA gz368 4 Dry L t6t •* ~`3r" ~ No ~ : r r ' "u~~d0~i~ v ' ~ ~~ nic ~ 1,~,3~~ "~ ~ .. ~ r ~ 'htn {." ~` :,~~~. < ,A napy ~. ",`T~CI. r ', S7r~ 4AC"u r9.v,.a.~~~~~ ri( X;~ ' o~w'"'~' :~~r ~.e.,.`:~,',» w'~.'.$... ~. _,S:o t» .::w . #".b h:r-'w<~ 1 a1~.Ntp,r ~~. TXI Oro Grande CA gz368 6 Dry t6t No t`'~"x`~7C~~.I+~x'1'»r,.... ,, ~I~r, ~,,:.n: .. .. W ~i ~ d,, ~`~~,'~?~ n;. kS~ilSuf~~n a"~~s'r`~~6 t,aw e.,~', ~~..» ~'.. .,~ir~i.'.. TXI Riverside CA 925og~~ t ~'~~ Dry 43 ~~ . ~ ~" No 1. W ~ ~ xarl ~ yy 12 ~, WW `Q 'H&' 'fib ~ t' ~iF Frv r.: `a.'de".i~"' w~rtakua ark», -;. y~~,~g~'- ply far ~,,, s '~Q Y ~S ~?;`4:.,I,M?c. ;'`' '~~efsl~~'v 5r ...,~,.,e;. °~''~~ ,~a. d%!',.• ^~u~iR. 7~"A~~~d`,~~. °~yn^u+,: d.., •'1~°r.''J. ~ "`~k.e %`.. i ~. a.-.'~~''. ~`. ~.. ~~ .. 5~ ,fir Titan Troutvilie VA 24175 t Dry 1,238 6 No America x«, u ~ w s~ ~ ~I~~ 4 . ~ t r'i"y"i r " r u: *rrvA ,.u ` a ;~ r u nM ~ ~ r ` ` a4 ~x~ ^ t~''~' zu'v~. w~ v a! 4Y Rte- x Nn n x A"M1mA +qp, ~ '~. ~~ ")V rrxr'~I'~ ~m t.. Medle7~.~ x ;~~.~^+~qd78;~p~ ~~~.e'" ~r ~~ , ~~ ~ d~Y~4 y, s~„. ,~...~ r .*f ~p~ rr ; ,.`, +. b.:. America, )a_ y,_ .w,..!.»~ as .av+Y'~r -. ~ a.'-~ _rf;, ~.~ .. W .,.~kr~w.~,...r n4,.,. ~, s,. >.-~, w t ~,.d.. ~^t~:t., Totals 252 ~ 82.512 4.692 9.829 ? r ~ ~23.43~ 27.5?t Notes 1. 'IWO plants in Puerto Rico not included. 'Ibtal number of A.ilns = 151. Tocal clinker ca pacify = 81,512,000 metric cons/ yr. 2. Data ocher than TRI was available for kilns with roughly 35 percent of the clinker capacity of non-hazardous waste kilns. 3. TRI data do no[ appear to be reliable. 4. Current best estimate for na[io nal (48-state) mercury emissions from non-hazardous waste kilns is between 6-13 tons/year. 5. Analysis is based on best available data; however, significant data gaps exist. Apend ix B Kiln Data Analysis Methodology Data Sources Considered and Methodology Data on mercury emissions were as- sembled and estimated from a review of the following sources: a. U.S. and Canadian Portland Cement Industry Plant Information Summary, December 31, 2006, which provided lists of U.S. cement plants and kilns, including clinker production capaci- ties. This report also identified certain kilns as burning only waste and these were excluded from the analysis; b. List of hazardous waste burning kilns from EPA (2005). These kilns were excluded from the analysis. c. Data obtained from EPA on several large cement company kilns in re- sponse to EPA's information collec- tion request. These data generally included: (i) source test reports including mercury tests. However, in many cases, source test data were over five years old. Only source tests that were no more than five years old were considered. In the vast majority of cases, clinker produc- tion during source test time periods were not provided and mercury emissions were reported on a di- rect mass rate basis (i.e., lb/hr, etc.). The methods used to test for mercury also varied. Older tests generally used EPA Method 29 while some o£ the more recent tests used the Ontario Hydro or similar methods. Representativeness of test data, extrapolated to annual operat- ing periods, is often questionable. All of these issues notwithstanding, source test data, where available, were u::ed to estimate annual emissions, assuming that kilns op- erated 1'or 90 percent of all hours in the year. If separate emissions rates were measured with raw mills on and off, these were accounted for in the calculation. (ii) data on mercury content in input (raw) materials to kilns for an approximate 30-day period dur- ing 2007. Although the mercury speciation data for 30 days was provided in several cases, in many cases, actual mercury values were noted a.s Non-Detect. These data often c~~uld not be used since cor- responding detection limits were often not noted. Also, in most cases, the mercury speciation of the clinker or baghouse dust was not available. d. Data on mercury air emissions sub- mitted to the EPA as part of the TRI Form A re~~orting. TRI data were used only if additional (i. e., mass input or source tesr) data were also available. The calculation methodology for TRI air emissions data are not readily apparent. In some cases, there were obvious pz~oblems with the TRI data (such as air emissions reported as zero, while source test data indicated non-zero values). e. Title V air operating permits for various operating kilns. These were reviewed to determine if there were specific mercury limits for particular kilns. Witri almost no exceptions, cur- rent Title 'V permits for kilns consid- ered in this study do not contain limits on mercury emissions. 29 Y. :~ 30 m: =c Uncertainties Data from these various sources, wher- ever comparable were not generally consistent. Therefore, to provide an idea of the uncertainties in emissions estimates, low and high ranges for expected annual mercury emissions are provided. While, in some cases, ~.he spread between the high and low values is not significant, in a few notable crises, this spread is exceptionally large, re fleet- ing large uncertainties as to underlying data or kiln operational details. All emis- sions data are reported as total mercury emissions; however, it should be no~=ed that based on the test methods used, it is not clear if all mercury species were completely measured. Thus, one area of possible uncertainty is the fracticn of mercury emissions emitted that are actually measured. Separate from emissions uncertainty, a couple of additional areas of uncer- tainty include: Kiln size (clinker capacity) was not always consistent considering similar data in the PCA report and that sub- mitted to EPA (even accounting for the fact that PCA report capacities are in metric tons and data reported to EPA was in either metric or U.S. customary (short) tons). n, Whether or not a particular kiln burns hazardous waste was, in some cases ambiguous. 'lb the extent possible, the analysis attempts to conservativcay exclude any kiln that may burn haz- ardous waste from this analysis. Overall, mercury emissions datrx, sub- ject to the caveat relating to speciation, were estimated for roughly 35 percent of kilns (based on clinker capacity). The emissions for the universe of kilns in the U.S. (excluding two kilns in Puerto Rico) were then extrapolated using clinker capacity. While this extrapolation •ar scaling is admittedly a rough attempt to estimate the U.S. kiln mercury emis- sions, at this time, there does not appear to be a more reliable method to prepare this estimate, other than relying on TRI data which has some clear flaws and therefore seems unreliable. Recommendations Recommendations for improving the mercury emissions estimates include the following: a. Clear identification of kilns that burn hazardous versus non-hazardous wastes; b. Completion of source tests under documented representative conditions, using standard methods that account for all species of mercury likely to be emitted; such source tests should also document the underlying production levels at the time of the test(s); c. Obtaining the data above from all kilns in the U.S. EPA's attempt to focus on the larger, national cement companies, while a good start, left out many com- panies that may be smaller or regional but still operate very large kilns; d. Inclusion of requirements to conduct source tests in facility operating permits such as Title V permits; e. Increase standardization and transparency of TRI data submittals; f. Improve the ability to conduct mass balance calculations by inclusion of mercury data in all input and output streams from the pyro-processing system, over time periods that reflect representative, relatively steady-state, operations of the system. If mercury is not detected in a particular stream, the appropriate detection limit should also be reported. Appendix C NORMALIZED MERCURY EMISSIONS FOR EXISTING AND NEW CEMENT KILNS" Hg Emissions (Ib/t,ooo,ooo ions ' FacID KiInID total feed) Kiln Capacity (tpy) Kiln Type Alkali Bypass CKD Wasted 4: t 4 ,, r m`M Se y[i-0 JLb 4 ti•^~Y Y kf` ~~'VVi ~'~fi ~i i u } j[ A ~~i°'~.I~h'Mh yp.~ ~t~~' s ~ $ ~ .a ~~3 ~ 3 ~ ` ~~ ~ ~ f w ~ 5 ~ ~ ~ , W ~ J.. .iV"~ .} , s. .e C..l.n ~.i l~ .Qia{t a~k"",. +vi U..Fvl~' 5 .. zh W ' m1 YU I. ~'.c f• { . ~ v ... 4.v n 2.35 t56, z 36 wet 6 z y ~y 4 :Mr~r+"y ~4wR~ ~+6'~f x i4r.,~~; >, ~?~ kc1 ~$°~:,p~ ~ :,,. ~ Q y vo lm A~4 d~7 Qt : - ~a "°R ~ b ~ ~ ~ " ' ~~ ' r ,. "sfi. r.-P n E.~^a.,.~. i.,+., va... ... .~ i rr-,~~d^ ~r3 t. .3aa ~ 3».+ n FA ~4as~,. .~ T .cs~s . ~ z6 r 2.43 340,956 preheater a`. :'vYeL :" ° , ,~} z?! ~;~ ~ y }§•8~~~85 ~~ gx~~~~b ~'~ 54 ~ ~l ~ ~ y ~" ~~~ ' ~ s ,y , ~ .5. _~ + r y w y.. M L .. `, ,. t . ~'. . .. .~. ,. I 5 ~ 2.65 334•t 6t wet ~ ,_ . t z6 2 7.55 602,434 preheater/calciner ~` +f :l0{1$ dXy "` z5 °" ~Ktt i %33i?~t ~ : 7~~ ~ ` ~ ~ ~" ' ' a , : . : ,. t . r, rx ., ~ , . i~ . . ,~ 36 Kiln t tzg6 652,568 preheater ~ ,M-~x r '~p'~$~ ~jsng~S)Ii'f ICfln t" ~~87~ .°r ~ '~~ ' x X •. ' i . . -x 39 . ° I , ,. . ... 39 Kiln z 23.87 420,480 long dry X ~m~ i K l ~tv ~ ."x ""` ~;'~~~4~» (~° ° :' ` « ~"~ 2 ' ~' ? ;~`~ ~ " r~ ? ~~r ~ ~ . ~ ti 3 , .:; . . ak ~> .F ~.~ x . ~.,,wrL~ 9: ^ ~, ~5 ~i ~r~ ~" s. # .~# s , a , .~ 3z Kiln z z4.7t r6g,756 wet X ~'~ ~. ,. r.,:`- ~ ,,.. ~:~: , k~ r t4 w - I'' ( t ~ I ~ "~'~ dlr "x,}~F ' ~ C'W ~'~y . : + .., w?Xv?> S~,..o:..:. .,?. A . . . ... I iii . e~. a .fAH ~ X r8 3 34.37 1,oz8,57o preheater/calciner X x+},,p+ p ~~ppQpp~~qp " `~F R":A ~: rroW, k:: ,y~@ `R .,, L 1:Y.%a ,• 6" ~ • ~ 9 M~ ~~ "~ FM"~9C 94'4. ~ t~'„v. ~* *~. ~'.~i ~'~ ~ C g " y,•- r 7 11 .. s.:.. ..:. Y..M,>.i a f.r. . . ~ ,'~ .a..H ~ i'YykT'. ~ .5 :.. ::wr r& '..,.uv .. ._ : .. .~:-,.:; ~'Fk ' ~ d i x .l ~ 34 Kiln 7 37-78 zzg,z8t wet X Ip +K• 3! T pp~~y.u Y:' S ~, rytryt~q~ •. f' e3~F:Y +~ aGi ~. X..+~4 Y'~~ ~ ~ q, F 1 E'{" ~, :4 ~ F w4~' y ~ ' : b ~- ~ ~ ~ '~g f R ~A^r ~ ~ ~ ~ ~ " "" ~ ~ Gµ1 w"ri-'! F A J l .; + - NMi; ~ _ "^'G . ..,•, i., ., , e ; ~~^.~ " ,;h J: ,'..&;. .~. uv , . r :~~ .w. +4dL ' 'Y "ax . , z2 z 43.74 t•t 25.746 wet long X X z -. ~I~i[ni " .. ~d7.3`9 .., 6oo,b`tSt~ pre7teaEe~ ", . ". ,'''' ~.°~ z Ktlnz 47.59 600,000 preheater 30 :. t 49'97~~i'~ 3. ',rx , ^~b74c;8~ja ~ . i~"r'lcalcfher".'.k ~ ,l;'~~ ~Ia ~ ~ -. 34 Kiln 8 48.ot z29,28t wet X w. ~, Wk x (~' ~ k+ P Pi ! 1 A W a 4~ yY i 'M• 'Sy M A~ A. I.,P 9 4 1 % -f j^{ I ~, ~ °~ . ~i9r x w~ 3 ~">. x .a 6:{~~__~~44 I ". "ryet )dreg " r ~ ~ 32.`- nv , ,I. . ~ ~~ t 93 ^ti~ " ~ Q ' Z . I ' ~,;x . , , i , ~ "7 . r.,. a ..,. sd k,: Jal .. z+ ~w ~'W.K 1 fi Nn,~Y kr.. 4 ~ a ~ ..l_.ri . 37 Kiln t 5r_r6 328,489 long dry ..^~: kr J.~h"4 xi c rwsx ,~ r~ s'r 4 ~~,`„ r r, v'. a59~_,xu . ''i~'t;~34jr~37r~'~n~ e~~ `Net} ;' tz-.. v~3~: fi : ''~ ~ '+w~ ^ ~ ^ A ' °, .._ .:: : , ~ .'i . , . .~ , -- ,~. er: ~. a . , r "sir< ater e 53-zg t,4i 0,958 preh 35 Kiln r ~A yy~ ~.~] J $~l f 3~~ fi~A ~Y~~~ ~ ~ II'~ ~I~ dyy ~'~ ~" ~~ ~ ~ s " ~ ~'' $ ? ~ ~ r ~ ~ ~ ~ ~ ' ~ " ~ X ~~ ~~+~. r o 3 , r O . & _ + B r.,v x. , ,tii -n '. A ., N R. a l . +tit . a 'r•az ,:n GP n~a:... k ~+. ~ . 4I , ~ l a~ ~ ~ ~?F • , /... - 38 22 54•t6 768,048 long dry X 38 :.'R3 '" ,t" r~4~•t~~~. S ~ s ~766~'u.~~F ~ 'long dry ... r„ X. 38 zo 54n6 g4o,857 long dry X r yo'ilg'dr~~"`ii t'~r~~~~~ 38 31 ~, s F 7g "~ °- ~a "~~5 r ~ . . A..y.i - " . , _ i „•v .a v'b ,v'am .,. :_b : ,~ .. .~. . , 37 Kiln 2 58.79 684.535 preheater X .q^y .9` ,~..yy S w p~ 1y~X K }MxA.. ~.~~LL..+,,~M ! MahH'4y~~.:. .`~y'+i *35CW1~y~sl^~ Cc y~FYi Wb~ 5 3n I'ryMy~~yg~,~y~yy~y~` ~u+P' I '7"N ."F• , pMC 1b:. r. .. , , } ~. lO ~4 J' '. ' ' " ~ " ~ ~ ~ ~~ ~~ N "~ ~ b ~ ,~ :: '~' ~ ~ f "~ ' ~' '~ a z5 ~+~ IRZ . S i4~"o, ~ . -.v 'K-~N ', / .9~.'8A1 , u~ u.*'~f1F;+xal 'h5u u~~,". ,~r. ; . ~n~i a. ~iN~ /" u.'fi . 9 x.r r.~ .J..?I wvxJ ..a.414 ua+ { I ~ ~ sai h , v. G , M i ro t 66.39 600,000 preheater 31 ~: 70 :.T. ' Consist of data for 54 kilns where no claim of confidentiality was made b,y [he submitting company. Note: EPA provided the data included in Appendix C, identifying particular kilns by their Facility ID number only, refer- enced here as "FacI D." 32 Hg Emissions _ , _ _ , (Ib/t,ooo,ooo tons FacID KiInID total f.~eed) Kiln Capacity (tpy) Kiln Type Alkali Bypass CKD Wasted ",¢xz4'.~`a ~ „a4iKdrt,3 M+. v"~~~.°'r7Sdi~S+S.oil;'~~~':e,T.~'„M~2.....,»~(it~5~ i,~~'^~y ~1 "P.ief~ea4er "i.' ,'-~ ~~',. ,;"1T. ~.u7•-1• ~s z4 Kiln z 66.59 +~~y 540,!44 preheater t ~z~"~;?; fF~. r&~~1 ~k75~Z~'~r<~#t' M ~~,~ m. ~~i't~~,.~j1Y e~V"e5t~r/ta~Cf•1~eF ^I' "~~ )~ ~<YS `x r ,.k - 3i Kiln i 76.y9~~zr yzi 8,z58 ,~„~ wet X 16 - a"kx°m ~ z .: ,i°ak&~P., :M~'~~JY?'~Y,~"m'F~t ~"^. "aid' *~,,~i~:U». ''t3~ ~~8~` 15~:"i a '4~°1''.~~4')TC~a~e~". ":.. ~ ,. ~.~. '~.X :Errs 3i Kiln z 8z.oo zi S,z58 wet X s E i d WY G 4 i, ,. y '. 3 • i _ i6, in ~,y t ', "i ,`'~ ~° r ~:.~ '~.; Bj~AY., lad ~'.~'3 ~'~ r327 7R~5 . Y ~~~'.t '41. r~'TPrefti`"A~el" ds"' .. M"inei.. F,$"~ a`JC ~ ~ _ , `. ~9 ~ 83.83 i,og5,ooo preheater/calcner it " i 88.0. i `66".531 .x'(?re~e3tby ::. ' , z~ 5 88.33 i,56o,00o preheater/calciner 4 Y tMep 4L '(," ~.:mE + vxk a fed„ r' a - p 'y 33: bm I~, f!rKll(i'4° W,.. -." ;". 9K'+~,a'~~ E.' . g'#'''?1 n 26«i~A r .. ' ~ ,'na we~ e+ a~ ru^ :j vu~ W, ~:,w a ;i~~ •.• ~ ,.,~. _ .;iM rn- ~ ISM S. z_. •' ,.d~ - "n^ 233 Kiln i io8.t5 5Yi,374 wet Y7 vt°~^~r rw~,.w ue4 v u' ,~vw..:eu" :... ::~. ~ .. F....<a.. ,d ~ ~_~~~II;Ief~C .. ..~! i,§v lL ~~`~ti ~~'" ( Fs.,.v a"r„1"Y:5 s".,~N i3 Eoz-ooi ~ izo.88 z,zzo,9i4 preheater/calciner y31 N~:<`~ ° ~ Y a iUiia?.~^~t ~ =w p ~1p~~{ ~ ~gtF ~s.,~ Wv,. 55 Ri r r a.i i ry ~,.. ~'~ ~», a,~w f .''. ~ .. n 33 '~.:yt"~'Rr N~#y~)n~Y"~ak ~1v'~'~S„w~N~ ~,. ~P. .P,. , ~~tlNF7k°'°rM"'.~~'r ~''?~ ~~' f ~. S.vs,. !`y.. ~r > 9 8 zzo.44 985.:73z preheater/calciner X X i ~ "~ d ,""'s ~~~< F ~ J ~'pi ,~~ ~r;R ' ~ ` ,f '• ~ `rc .~ q ~ w'i r ~» uu. ~ry ~. i • y`. 9... ,-. _~~~,.fr~9'~a'~7.. ~.. mn4~»~'~r..°.r.~<B#Sae,E'#r~'7i~anEt -did, r_ z8 i i,98z,oi g66,~5gz precalciner Total Capacity (tpy clinker) 3z,o8•;,6i4 ',Totaf,MCr~u;ryBr,~tssioia"7(fbJyr) '~~."~'!~.jr7~c oo , .. ,. Mercury Emission Factor (Ib/tpy capacity) o.ooo 'Estimai6d=,Natia"nwt°de (v5ert'~C.iy~E"ir'tisisrt~s'`tlti/~+~'~~a~r~ ~';'"~2'i~ cli8'~